laporan kimia lingkungan tph

7/24/2019 Laporan Kimia Lingkungan TPH

1/21

LAPORAN

PRAKTIKUM KIMIA LINGKUNGAN

ANALISA TPH (TOTAL PETROLEUM HIDROKARBON)

PADA TANAH TERCEMAR MINYAK BUMI

DENGAN METODE GRAVIMETRI (USEPA METHOD)

Oleh :

1. FARIZ ANZHARI KWANDA (1407122446)2. MUTIA KHAIRUNNIA (1407114!24)

". NURUL AUDINA (1407114#"6)4. RI INDIRA PUPA P$RTIWI (1407114717)

DO$N :

$DWARD. H

AIT$N :

%ONNA %UNITAARI

PROGRAM TUDI T$KNIK LINGKUNGANFAKULTA T$KNIK

UNI&$RITA RIAU

P$KAN'ARU

201#


2/21

BAB I

PENDAHULUAN

1.1. Tujuan P!"#$aan

1. Me**l+,* -*/* +*-** 3**h

2. Meh+3/ -,e35*,+ +*- ** 3**h 3e5e*5

1.%. Da&a! T#!'

A-3++3*, +/,35+ e5+*-* (ee85*9 e+l**9 5,e, 5/-,+ *35*,53*,+) //* eh*,+l-* l+8*h +*- * 3e5*+ 3/*h* 8*+-

+3**h *// e5*+5*. L+8*h 3/*h* 3e5,e8/3 *-* ,e*-+ e+-*3 ,e*l*

e* e+-*3* *-3++3*, +/,35+ e5+*-* +l*** (U+h*539 1;;6).U,*h* e*/l** +*- 8/+ ,e*5* -e,+*l h*,+l* -/5*

e/*,-*. Me8/* 8*h* ee*5 +*- 8/+ -e3**h **3

e*-+38*3-* 3e5e*5* 3**h9 +** 3**h *-* e*+ 3*/, e*

3/8/h* e-,e5 +3**h * e* e8e*-* -e*l* 3**h 3+*-

e*/l*+ *,*l*h9 8*h-* **3 e5e,* -e *+5 3**h * ee*5+ e5*+5*.M*-* /3/- /,*h* el*h* 3**h 3e5e*5 +*- 8/+ le8+h l*/3 e5l/

+l*-/-* **l+,* -*/* +*- * 3e5**3 +3**h 3e5e*5 3e5,e8/3 /3/-

+*5+-* ,l/,+ le8+h l*/3 (8+5ee+*,+). Ke8e5*** l+8*h +*- +3**h h*5/,

,e,/*+ e* -5+3e5+* +l*+ *-h+5 * +e5-e*-* /3/- +8/* -el+-/*

,e,/*+ e* e5*3/5* e5/*? (K$M$N LH N. 12! T*h/ 200")

T#a P!#u* H'+!#,a!$#n (TPH)

Pe35le/ 8e5*,*l *5+ -*3* petra * *53+* 8*3/ * oleum * *53+*

+*-. Pe35le/ e5/*-* */5* -le-,. Pe35le/ 3e5+5+ *5+ ,e*=*

h+5-*58 (;!@)9 /l/5 (1 B "@)9 N+35e (C 1@)9 O-,+e (C 1@)9 L* *3*/

+e5*l (C 1@)9 G*5* (C 1@). Me/5/3 $PA (Environmental Protection Agency)9


3/21

e35le/ h+5-*58 8e5*,*l *5+ +*- e3*h (crude oil). Crude oil ++

+/*-* /3/- e8/*3 5/- e35le/9 * **3 ee*5+ l+-/*.

'e5*,*5-* ,/,/* le-/l +*- 8/+ *-* ,e*=* h+5-*58 **3

+-el-* e*+ e*3 l* (Rel,9 1;6") :

1. P*5*++- (Al-**) : H2E2

P*5*++- e5/*-* e5,e*=** h+5-*58 e/h e* 5*3*+ *3

3e58/-* * 3e5+5+ *5+ 5*l *5*+ * *5*+ *8* (+,e5).

2. N*3e+- (+-l*5*+) : H2

N*3e+- e5/*-* e5,e*=** h+5-*58 e/h e* 5*3*+ *3

3e53/3/ * 3e5+5+ *5+ 5*l *3e (*3e * l+*3e) * *3e

8e5*8*. 3h* *+3/ : +-lhe3**

". A5*3+- : H2


4/21

#. Te-** /** le8+h -e+l *5+ ,*3/ *3

6. U/* 8e5*/

7. Me+l+-+ *,,* 5el*3+ ,e8e,*5 2!2

!. Me+l+-+ 3+3+- leleh ,e8e,*5 "7

;. Me+l+-+ 3+3+- ++h ,e8e,*5 ("00


5/21

4. Mineral Oil

Mineral Oil,e5+ +,e8/3 ,e8**+ +*- el/*,. I-*3* -*58* *3*5* 1#

,**+ #0. Mineral oil8**- +/*-* ** -e*5** 8e535. H+5-*58

* 3e5-*/ *3*5* l*+ *l-**9 ,+-l*l-**9 * h+5-*58 *5*3+-.

TPH Ba' K&2aan Manu&'a

ee53+ +el*,-* *l* ,+*3


6/21

*l* *5*h 3e53e3/ * + *l** *3


7/21

Ke,3*8+l* ,/h/ 8*+-

Re3* ,/h/ le8*5

D**3 +/*-* /3/- **l+,+, +,3e5*l * **l+,+, ** ,/h/ 3e555*

. Kl

Kl **3 ++8*5*3-* ,e8**+ *3/* -5*35*+. P** -l ++l*h

3e5*+ e+,*h* -e ** ,*el. e*5* // -l * le8+h

** **3 e+,*h-* le8+h 8*+- */ =*-3/ **l+,+,* e*+ le8+h

l**. e*-+ -e+l +*e3e5 *l* ,e*-+ 8*+- e+,*h**. Kl +8/*3

,+5*l /3/- ehe*3 3e*3. A* /* e+, -l *+3/ -l -e*,* *

-l -*+le5.

e. De3e-35

De3e-35 ** -5*35*+ **l*h ,/*3/ ,e,5 ele-35+- * 8e5/,+

e/8*h ,+*l *, e8*=* * -e


8/21

Pe35le/ h5-*58 * +*-,/-* *l* Kee 12!?200" **l*h

,e*=* * 3e5**3 ** +/,35+ +*, * +h*,+l-* *5+ +/,35+ +*,.

De* e+-+*9 -e8e5*** ,e*=* ++ ** *e5*h +/,35+. e53+8**

-,e35*,+ *8* 8*3*, /3/- TPH +/,35+ +*, +*,*5-* ** 53e-,+

3e5h** 3*** * ,/8e5 *+5 (*+5 3**h * *+5 e5/-**). H*,+l ,3/+


9/21

/* **3 ee*5+ /*5* * 8e58*h** 8*+ -e,eh*3* */,+* 8+l* 3e5h+5/

(A+9 201").

BAB II

METODOLOGI PERCOBAAN

1. Aa

Al*3


10/21

K** A5l+

Ke53*, *5+

$5leee5 2#0 l

De,+-*35

P+e3 Te3e,


11/21

'*3* Pe*/-

Al/++/ F+l

Gel*, U-/5 100 l

Oe

%.%. Ba2an


12/21

'*h*


13/21

2. *el 3**h +*/5-* e* 100 l


14/21

4.1. Ha&'

N# P!a,uan Ha&'

1 *=* e/* +3+8* 679"00 5

2 10 5 ,*el 3**h * 3e5e*5 +*- 8/+ W*5*: -el*3 3/*

" 100 l


15/21

449427 5

'e5*3 5e,+/ ,e3el*h e**,* ,el** 4# e+3 A B ' 6!9172 5 B 679"00 5

09!72 5

'e5*3 5e,+/ ,e3el*h e**,* ,el** 1# e+3 A B '

679"67 5 B 679"00 5

09067 5

'e5*3 5e,+/ ,e3el*h e**,* ,el** 1# e+3 A B '

679"6; 5 B 679"00 5

0.06; 5

@ TPH berat residiuberat sampel

100

0,069gr

10,007 gr100

096;@

De*:

A 8e5*3 *=* ,e3el*h +**,-*

' 8e5*3 *=* -,

".2. Pe8*h*,*

P** e58**9 /l*


16/21

e*/ *+5. Pe*8*h* N*2O4 *h+5*3 *-* ee5* *+5 *

*,+h 3e5**3 ** +l35*3e -*5e* *** *+5 **3 ee8*8-*

3e58e3/-* 5/- *3*/ 5e*-,+ * 3+*- +++-*. N*2O4*h+5*3 3+*-

l*5/3 * ee* + *,*5 e5leee59 -e/+* +,*5+. H*,+l ,*5+*

*+3/ l*5/3*


17/21

LAMPIRAN

G*8*5 1. *el 3**h 3e5e*5

+*- 8/+

G*8*5 2. F+l35*3 +3*8*h

N*2O4


18/21

G*8*5 ". F+l35*3 + *l* *=*

e/* ,e8el/ +**,+

G*8*5 4. Re,+/ ,e3el*h

+**,+ ,el** 4# e+3

G*8*5 #. Re,+/ ,e3el*h

+**,+ -e8*l+ ,el** 1# e+3


19/21

G*8*5 6. Re,+/ ,e3el*h

+**,+ -e8*l+ ,el** 1# e+3

* +e5leh 5e,+/ * 3el*h

-,3*.


20/21

BAB IV

KESIMPULAN DAN SARAN

7.1 K&'*3uan

A*l+,* TPH e5/*-* ,/*3/ *5* /3/- ee3/-* -,e35*,+

+*- 8/+ * ** + 3**h.

Pe5,e TPH 8e5*,*5-* h*,+l e58** *+3/ 0.6;@. Me/5/3 Kee

N5 12! T*h/ 200"9 -,e35*,+ TPH *-,+*l **l*h 1@ ,e3el*h

+l*-/-* 8+5ee+*,+. H*l ++ e//--* 8*h=* ,*el 3**h 3+*-

3e5e*5 +*- 8/+.

7.% Sa!an

e8el/ 5*3+-/ he*-* e*-*+ *, l*89 *,-e59 * ,*5/

3** **5 3e5h+*5 *5+ *3


21/21

A+. 201".!ioremediasi dan Total Petroleum"

h33:??===.8+5ee+*,+.8l,3..D+*-,e, ** 12 Ne8e5 201#.

D*9 R. A. * A. L. Ue5=. 2002.Analisis #imia #uantitatif. $+,+ Kee*.

*-*53* : Pee58+3 $5l**.

Rel,. 1;6". Physical Chemistry of Petroleum $olvents Reinhold" Ne= %5-:

P/8l+,h+ 55*3+.

U+h*539 M. 1;;6.Peranan !ioremediasidalam Pengelolaan %ing&ungan.

Prosiding Pelatihan dan %o&a&arya. +8+: Le8** Il/ Pee3*h/*

Ie,+*.
http://www.bioremediasi.blogspot.com/http://www.bioremediasi.blogspot.com/http://www.bioremediasi.blogspot.com/

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