spm percubaan 2007 mrsm chemistry paper 3

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    [See Next Page

    Name : ..... Index number : ..

    Class : ..

    CONFIDENTIAL

    ChemistryPaper 3

    September

    2007

    1 jam

    SPM TRIAL EXAMINATION 2007

    MAKTAB RENDAH SAINS MARA

    CHEMISTRYPaper 3

    One hour and thirty minutes

    DO NOT OPEN THIS QUESTION BOOKLET

    UNTIL BEING TOLD TO DO SO

    1. Write yourname, index number and class

    in the space provided.

    2. This question booklet is bilingual.

    3. The question is in English followed by the

    Malay version.

    4. Candidate is required to read the

    instruction on page 2.

    For Examiners Use

    QuestionFull

    Mark

    Obtained

    Mark

    1 33

    2 17

    Total 50

    This question booklet contains 13 printed pages.

    INFORMATION FOR CANDIDATESCONFIDENTIAL4541/3 2007 Hak Cipta MARA

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    INFORMATIONFORCANDIDATES[MAKLUMAT UNTUK CALON]

    1. This question paper consists of two questions. Answerall questions.

    [Kertas soalan ini mengandungi dua soalan. Jawab semua soalan]

    2. Write your answers forQuestion 1 in the spaces provided in the question paper.[Tuliskan jawapan bagi Soalan 1 dalam ruang yang disediakan dalam kertas soalan]

    3. Write your answers for Question 2 on the lined pages at the end of the question

    paper in detail.

    [Tuliskan jawapan bagi Soalan 2 pada halaman bergaris di bahagian akhir kertas

    soalan ini dengan terperinci]

    4. Show your working, it may help you to get marks.

    [Tunjukkan cara mengira kerana ia boleh membantu anda mendapatkan markah]

    5. If you wish to cancel any answer, neatly cross out the answer.[Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas

    jawapan itu.]

    6. The diagrams in the questions are not drawn to scale unless stated.

    [Rajah yang terdapat dalam soalan tidak dilukis mengikut skala kecuali dinyatakan

    sebaliknya.]

    7. Marks allocated for each question or part of the question are shown in brackets.

    [Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan

    dalam kurungan.]

    8. The time suggested to complete Question 1 is 45 minutes andQuestion 2 is 45

    minutes.

    [Masa yang dicadangkan untuk menjawab Soalan 1 ialah 45 minit dan Soalan 2

    ialah 45 minit.]

    9. You may use a non-programmable scientific calculator.

    [Anda dibenarkan menggunakan kalkulator saintifik yang tidak diprogramkan.]

    10. Hand in all your answer sheets at the end of the examination.

    [Serahkan semua kertas jawapan anda di akhir peperiksaan.]

    Marks awarded [Pemberian markah]

    Score

    [Skor]Description [Penerangan]

    3Excellent : The best response

    [Cemerlang] : [Respons yang paling baik]

    2Satisfactory : An average response

    [Memuaskan] : [Respons yang sederhana]

    1Weak : An inaccurate response

    [Lemah] : [Respons yang kurang tepat]

    0 No response or wrong response[Tiada respons atau respons yang salah]

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    1 An experiment is carried out to determine the end point of a neutralisation process.

    50.00 cm3 of aqueous potassium hydroxide 0.1 mol dm-3 is titrated against

    hydrochloric acid with an unknown concentration using phenolphthalein as an

    indicator.

    The titration is repeated twice. Diagram 1.1 shows the results of the experiment.

    [Satu eksperimen telah dijalankan untuk menentukan takat akhir bagi proses peneutralan. 50.00 cm3

    larutan kalium hidroksida 0.1 mol dm-3

    dititratkan dengan asid hidroklorik yang kepekatannya tidak

    diketahui dengan menggunakan penunjuk fenolftalein.

    Pentitratan diulang sebanyak dua kali. Rajah 1.1 menunjukkan keputusan eksperimen.]

    Titration Set

    [Set Titratan]

    1 2 3

    Initial Burette

    Reading

    [Bacaan Awal

    Buret]

    cm3 cm3

    cm3

    Final Burette

    Reading

    [Bacaan akhir

    buret]

    cm3 cm3 cm3

    DIAGRAM 1.1

    [RAJAH 1.1]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

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    (d) (i) What is the average volume of hydrochloric acid used in the experiment?[Berapakah purata isipadu asid hidroklorik yang digunakan dalam eksperimen ini?]

    (ii) The chemical equation for the reaction is :

    [Persamaan kimia bagi tindak balas ini ialah:]

    Determine the concentration of hydrochloric acid used.[Tentukan kepekatan asid hidroklorik yang digunakan.]

    [3 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    1(d)

    KOH + HCl KCl + H2O

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    (e) The experiment is repeated using sulphuric acid to replace hydrochloric acid.

    It was found that the volume of sulphuric acid required is half the volume of

    hydrochloric acid used.

    State the inference of this observation.[Eksperimen ini diulang dengan menggunakan asid sulfurik untuk menggantikan asid hidroklorik.

    Didapati isipadu asid sulfurik yang diperlukan adalah separuh daripada isipadu asid hidroklorik yang

    digunakan.

    Nyatakan inferens bagi pemerhatian ini]

    .

    ..

    [3 marks]

    (f) Potassium chloride which is produced in this experiment is an example of a soluble

    salt.

    Classify the following substances into soluble and insoluble salt.[Garam yang terhasil dalam eksperimen ini ialah kalium klorida, sejenis garam terlarutkan. Kelaskan

    bahan bahan berikut kepada garam terlarutkan dan garam tak terlarutkan.]

    [3 marks]

    1(f)

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    1(e)

    Substances

    [Bahan bahan]

    Sodium sulphate Lead(II) iodide Barium sulphate

    [Natrium sulfat] [Plumbum(II) iodide] [Barium sulfat]

    Magnesium nitrate Zinc carbonate Silver chloride

    [Magnesium nitrat] [Zink karbonat] [Argentum klorida]

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    (g) Diagram 1.2 shows three test tubes containing potassium hydroxide solution with

    different concentrations and pH values.[Rajah 1.2 menunjukkan tiga tabung uji yang mengandungi larutan kalium hidroksida pada kepekatan

    dan nilai pH yang berbeza.]

    Test tube

    [Tabung uji]1 2 3

    Concentration[Kepekatan]

    pH value

    [Nilai pH]

    13 12 11

    DIAGRAM 1.2

    [RAJAH 1.2]

    Based on Diagram 1.2,[Berdasarkan Rajah 1.2,]

    (i) Give the operational definition for the pH value of an alkali.[Berikan definisi secara operasi bagi nilai pH untuk suatu alkali]

    .

    .

    [3 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    0.1mol dm-3potassium hydroxide

    [kalium hidroksida]

    0.01mol dm-3

    potassium hydroxide

    [kalium hidroksida]

    0.001 mol dm-3

    potassium hydroxide

    [kalium hidroksida]

    1(g)(i)

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    (ii) Predict the pH value if the concentration of potassium hydroxide solution is

    0.0001 mol dm-3.[Ramalkan nilai pH bagi larutan kalium hidroksida yang berkepekatan 0.0001 mol dm

    -3.]

    ............

    [3 marks]

    (iii) As the concentration of the potassium hydroxide solution changes, the pH value

    also changes. Explain why.[Apabila kepekatan larutan kalium hidroksida berubah, didapati nilai pH juga berubah.

    Terangkan mengapa.]

    ............

    [3 marks]

    (iv) State the variable involved in this experiment.[Nyatakan pembolehubah yang terlibat dalam eksperimen ini.]

    Manipulated variable: .[Pembolehubah yang dimanipulasikan]

    Responding variable: .[Pembolehubah yang bergerakbalas]

    Controlled variable: ...[Pembolehubah yang dimalarkan]

    [3 marks]

    (v) State the hypothesis for this experiment.[Nyatakan hipotesis bagi eksperimen ini.]

    ............

    [3 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    1(g)(ii)

    1(g)(iii)

    1(g)(iv)

    1(g)(v)

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    2 Equal volume of water is heated in two different kettles by a scout during camping.

    Kettle 1 is heated by using alcohol X while kettle 2 is heated by using alcohol Y as

    shown in Diagram 2. The size and type of both kettles are the same.[Semasa perkhemahan, seorang pengakap telah memanaskan air yang mempunyai isipadu yang

    sama dalam dua cerek berlainan Cerek 1 dipanaskan dengan alkohol X manakala cerek 2

    dipanaskan dengan alkohol Y seperti ditunjukkan dalam Rajah 2. Saiz dan jenis kedua dua cerek

    adalah sama.]

    DIAGRAM 2

    RAJAH 2

    It was discovered that the mass of alcohol X needed to boil the water is more

    compared to alcohol Y.[Didapati jisim alkohol X yang diperlukan untuk mendidihkan air lebih besar berbanding alkohol Y.]

    Plan a laboratory experiment to compare the heat of combustion between alcohol X

    and Y based on the above situation.[Berdasarkan kepada situasi di atas, rancangkan satu eksperimen makmal untuk membandingkan

    haba pembakaran antara alkohol X dan Y.]

    Your planning should include the following aspects:[Perancangan anda haruslah mengandungi aspek berikut :]

    (a) Problem statement [Pernyataan masalah]

    (b) All the variables [Semua pembolehubah](c) Statement of hypothesis [Pernyataan hipotesis]

    (d) List of substances and apparatus [Senarai bahan dan alat radas]

    (e) Procedure of the experiment [Prosedur eksperimen]

    (f) Tabulation of data [Penjadualan data]

    [17 marks]

    END OF QUESTION PAPER[KERTAS SOALAN TAMAT]

    Kettle 1

    [Cerek 1]

    Kettle 2

    [Cerek 2]

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    ForExaminers

    Use[Untuk

    Kegunaan

    Pemeriksa]

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    For

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    Forxaminers

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    For

    ExaminersUse

    [Untuk

    Kegunaan

    Pemeriksa]

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