spm percubaan 2007 mrsm chemistry paper 2

Upload: chinwynncom

Post on 31-May-2018

273 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    1/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    1

    Name : . Index Number: .......

    Class:

    SPM TRIAL EXAMINATION 2007

    MARA Junior Science College

    CHEMISTRY

    Paper 2

    Two hours and thirty minutes

    DO NOT OPEN THE QUESTION BOOKLET

    UNTIL BEING TOLD TO DO SO

    1. Write your name, index number and class in

    the space provided.Tuliskan nama , angka giliran dan kelas anda pada

    ruang yang disediakan.

    2. The question booklet is bilingual

    Kertas soalan ini adalah dalam dwibahasa.

    3. Candidate is required to read the information

    in page 2.Calon dikehendaki membaca maklumat

    di halaman 2 .

    For Examiners Use

    Section QuestionFull

    Mark

    Obtained

    Mark

    1 9

    2 10

    3 9

    4 11

    5 11

    A

    6 10

    7 20

    B 8 20

    9 20

    C 10 20

    TOTAL

    This booklet contains 31 printed pages.

    4541/2

    ChemistryPaper 2

    Sept 2007

    2 hour

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    2/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    2

    INFORMATION FOR CANDIDATESMAKLUMAT UNTUK CALON

    1. This question paper consists ofthree sections: Section A, Section B and Section C.[Kertas soalan ini mengandungi tiga bahagian:Bahagian A,Bahagian B dan Bahagian C.]2. Answer all questions in Section A. Write your answers for Section A in the

    spaces provided in the question paper.[Jawabsemua soalan dalamBahagian A. Tuliskan jawapan bagi Bahagian Adalam ruang yang

    disediakan dalam kertas soalan].

    3. Answer one question from Section B and one question from Section C. Write youranswers for Section B and Section C on the lined pages at the end of the question

    paper. Answer questions in Section B and Section C in detail. You may use

    equations, diagrams, tables, graphs and other suitable methods to explain youranswer.[Jawapsatu soalan daripadaBahagian B dansatu soalan daripadaBahagian C. Tuliskan jawapan

    bagi Bahagian B dan Bahagian Cpada halaman bergaris di bahagian akhir kertas soalan ini.

    Jawab Bahagian B dan Bahagian Cdengan terperinci. Anda boleh menggunakan persamaan,

    gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda].

    4. Show your working, it may help you to get marks.[Tunjukkan kerja mengira, ini membantu anda mendapatkan markah].

    5. If you wish to cancel any answer, neatly cross out the answer.[Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu].

    6. The diagrams in the questions are not drawn to scale unless stated.[Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan].

    7. Marks allocated for each question or part question are shown in brackets.[ Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan].

    8. The time suggested to complete Section A is 90 minutes, Section B is 30 minutesand Section C is 30 minutes[Masa yang dicadangkan untuk menjawabBahagian A ialah 90 minit, Bahagian B ialah 30 minit

    danBahagian C ialah 30 minit].

    9. You may use a non programmable scientific calculator.[Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan].

    10.Hand in all your answer sheets at the end of the examination.[Serahkan semua kertas jawapan anda di akhir peperiksaan].

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    3/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    3

    Section ABahagian A

    [60 marks]

    Answerall questions in this section.

    The time suggested to answer thissectionis 90 minutes[Jawabsemua soalan dalam bahagian ini.

    Masa yang dicadangkan untuk menjawab bahagian ini ialah 90 minit.]

    1 Diagram 1 shows the electronic arrangement of atoms of six elements.

    P, Q, R, S, T and U do not represent the actual symbol of the elements.

    Use the letters to answer the following questions.[Rajah 1 menunjukkan susunan elektron atom-atom bagi enam unsur.

    P, Q, R, S, T, dan U tidak mewakili simbol sebenar unsur-unsur berkenaan.

    Gunakan huruf-huruf yang diberikan untuk menjawab soalan-soalan berikut.]

    DIAGRAM 1[RAJAH 1]

    (a) Determine and fill the position of P and T in the Periodic Table of Elements givenbelow.[Tentukan dan isikan kedudukan P dan T dalam Jadual Berkala Unsur di bawah]

    Q R

    S U

    [2 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    1(a)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    4/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    4

    (b) State one element which:

    [Nyatakan satu unsur yang merupakan]:

    (i) is a metal: ..........................................................................................................[suatu logam]

    [1 mark]

    (ii) forms an ion with +2 charge: ...........................................................................[membentuk ion bercas +2]

    [1 mark]

    (iii) is used in advertising light: ...............................................................................[digunakan dalam lampu iklan]

    [1 mark]

    (c) Name the products formed when S reacts with water.[Namakan hasil-hasil yang terbentuk apabila S bertindak balas dengan air.]

    ........................................................................................................................................

    [2 marks]

    (d) State one usage of U in water treatment plant.[Nyatakan satu kegunaan U dalam loji rawatan air.]

    ........................................................................................................................................[1 mark]

    (e) The atomic radius of T is smaller than S. Explain why.

    [Jejari atom T lebih kecil dari S. Terangkan mengapa.]

    ........................................................................................................................................

    [1 mark]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    1(b)(i)

    1(b)(ii)

    1(b)(iii)

    1(c)

    1(d)

    1(e)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    5/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    5

    2 Diagram 2 shows the electrolysis of 1.0 mol dm-3

    sodium chloride solution which is

    still in progress.[Rajah 2 menunjukkan elektrolisis larutan natrium klorida 1.0 mol dm

    -3yang sedang dijalankan]

    DIAGRAM 2[RAJAH 2]

    (a) Write the formulae of all ions present in the electrolyte.[Tuliskan formula semua ion yang wujud dalam elektrolit]

    ........................................................................................................................................

    [1 mark]

    (b) Name the gas produced at:[Namakan gas yang terhasil di]:

    (i) burette X : ......................................................................................................[buret X]

    (ii) burette Y : ......................................................................................................

    [buret Y] [2 marks]

    (c) State how you would verify the gas named at b(i).

    [Nyatakan bagaimana anda mengesahkah gas yang dinamakan di b(i)]

    ........................................................................................................................................

    ........................................................................................................................................

    ........................................................................................................................................

    [3 marks]

    (d) (i) Write the half-equation for the process that occurs in burette X.[Tuliskan setengah persamaan bagi proses yang berlaku di buret X.]

    ............................................................................................................................[1 mark]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    2(b)

    2(a)

    2(c)

    2(d)(i)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    6/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    6

    (ii) At the end of the experiment, 30.00 cm3

    of gas was collected at room

    temperature in burette X.

    Calculate the number of moles of gas collected in burette X.

    [1 mol of gas occupies a volume of 24.0 dm3 at room temperature]

    [Di akhir eksperimen, 30.00 cm3 gas dikumpulkan pada suhu bilik dalam buret X.Hitungkan bilangan mol gas yang dikumpulkan dalam buret X][1 mol gas menempati 24.0 dm

    3pada suhu bilik]

    [1 mark]

    (e) Name a substance that can be used to replace carbon electrodes for the experiment

    to get the same result?[Namakan satu bahan yang boleh digunakan untuk menggantikan elektrod karbon bagi eksperimen

    menghasilkan keputusan yang sama.]

    ........................................................................................................................................

    [1 mark]

    (f) State one usage of the electrolysis of sodium chloride solution in industry.[Nyatakan satu kegunaan elektrolisis larutan natrium klorida dalam industri.]

    ........................................................................................................................................

    [1 mark]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    2(d)(ii)

    2(e)

    2(f)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    7/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    7

    3 (a) Diagram 3 shows a series of tests performed on a colourless solution which

    contains one cation and two anions..[Rajah 3. menunjukkan satu siri ujian yang dijalankan ke atas larutan tanpa warna yang

    mengandungi satu kation dan dua anion.]

    DIAGRAM 3[RAJAH 3]

    (i) Based on the observations in Diagram 3, complete the table below withappropriate inferences.[Berdasarkan pemerhatian dalam Rajah 3, lengkapkan jadual di bawah dengan inferens

    yang sesuai]

    Test[ujian] Inference[inferens]

    1

    2

    3

    [3 marks]

    (ii) Write an ionic equation for the reaction in Test 3.[Tuliskan persamaan ion bagi tindak balas dalam Ujian 3]

    ...........................................................................................................................

    [1 mark]

    + HNO3(aq) , AgNO3(aq)

    Colourless solution[Larutan tanpa warna]

    + NaOH (aq), then heated

    (+ NaOH(ak), dan dipanaskan)

    Vapour produced turns damp

    red litmus paper to blue[Wap terhasil menukarkan kertas

    litmus merah lembab kepada biru]

    Test 1(Ujian 1)

    White precipitate formed.[Mendakan putih terbentuk]

    Brown ring formed[Cincin perang terbentuk]

    Test 2(Ujian 2)

    Test 3(Ujian 3)

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    3 a i

    3 a ii

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    8/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    8

    (b) A student wants to prepare a pure sample of crystalline zinc sulphate by reacting

    dilute sulphuric acid with substance X.[Seorang pelajar ingin menyediakan suatu sampel tulen hablur zink sulfat melalui tindak balas

    antara asid sulfurik dengan bahan X]

    (i) Name the substance X.[Namakan bahan X]

    ............................................................................................................................

    [1 mark]

    (ii) Write an equation for the above reaction.[Tuliskan satu persamaan kimia bagi tindak balas di atas]

    ............................................................................................................................

    [1 mark]

    (iii) Calculate the maximum mass of zinc sulphate that can be prepared if 50.0

    cm3

    of 0.2 mol dm-3

    sulphuric acid is reacted with excess X.

    [The relative formula mass of zinc sulphate = 161][Hitungkan jisim maksima zink sulfat yang dapat disediakan jika 50.0 cm3 larutan asid

    sulfurik 0.2 mol dm-3

    ditindak balaskan dengan X berlebihan]

    [Jisim formula relatif zink sulfat = 161 ]

    [3 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    3 b i

    3(b)(ii)

    3(b)(iii)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    9/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    9

    4 An experiment is carried out to study the effect of concentration on rate of reaction.

    50.0 cm3

    of 0.5 mol dm-3

    hydrochloric acid and excess granulated calcium carbonate

    is put into a conical flask and is placed on an electronic balance as shown in

    Diagram 4.

    The mass of the conical flask and its contents is recorded at 60 seconds intervals.

    [Satu eksperimen telah dijalankan untuk mengkaji kesan kepekatan ke atas kadar tindak balas.50.0 cm

    3asid hidroklorik 0.5 mol dm

    -3dan ketulan kalsium karbonat berlebihan dimasukkan ke

    dalam kelalang kun diletakkan di atas neraca elektronik seperti dalam Rajah 4.

    Jisim kelalang kun dan kandungannya direkodkan pada sela masa 60 saat].

    DIAGRAM 4RAJAH 4

    Table 4 shows the results.[Jadual 4 menunjukkan keputusan]

    Time/sec.

    [Masa/saat] 0 60 120 180 240 300 360 420 480Balance readings /g[Bacaan neraca/g] 140.64 140.48 140.37 140.31 140.26 140.22 140.20 140.20 140.20

    TABLE 4[JADUAL 4]

    (a) Give the definition of rate of reaction.[Berikan maksud kadar tindak balas]

    ........................................................................................................................................

    [1 mark]

    (b) Explain why the mass of the conical flask and its content decreases with time.[Terangkan mengapa jisim kelalang kun dan kandungannya berkurang dengan masa]

    ........................................................................................................................................

    ........................................................................................................................................

    [1 mark]

    (c) Based on Table 4, plot a graph of the mass of the conical flask and its content versus

    time on the graph paper below.[Berdasarkan Jadual 4, plotkan graf jisim kelalang kun dan kandungannya melawan masa pada

    kertas graf di bawah].

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    4(a

    4(b)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    10/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    10

    [3 marks] 4 c

    Graph of mass of the conical flask and its content versus timeGraf jisim kelalang kun dan kandungannya melawan masa

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    11/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    11

    (d) Based on the graph, calculate the instantaneous rate of reaction at 120 seconds.

    [Berdasarkan graf, hitungkan kadar tindak balas pada saat ke 120]

    [3 marks]

    (e) (i) Calculate the mass of carbon dioxide gas produced.[Hitungkan jisim gas karbon dioksida yang dihasilkan]

    [1 mark]

    (ii) Calculate the expected volume of gas produced at room condition.

    [1 mol of gas occupies 24 dm3

    at room condition; relative molecular mass of

    CO2 is 44 ][Hitungkan isipadu gas yang dijangka akan terhasil pada keadaan bilik.

    1 mol gas menempati 24 dm3 pada suhu bilik ; jisim molekul relatif CO2 ialah 44]

    [2 marks]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    4(d)

    4(e)(i)

    4(e (ii

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    12/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    12

    5 Diagram 5 shows a series of chemical reactions starting from compound Y.[Rajah 5 menunjukkan satu siri tindak balas kimia bermula daripada sebatian Y]

    DIAGRAM 5RAJAH 5

    (a) Name compound Y[Namakan sebatian Y]

    ........................................................................................................................................

    [1 mark]

    (b) Draw a diagram to show the set-up of apparatus if Process I is to be carried out in a

    laboratory.[Lukiskan satu rajah untuk menunjukkan susunan radas jika Proses I dilakukan dalam makmal]

    [2 marks]

    CH3CH2COOH

    Compound R

    [Sebatian R]

    Compound P[Sebatian P]

    C3H6CH3CH2CH2OH

    Compound Y[Sebatian Y]

    Process I

    (Proses I)

    Process III(Proses III)

    Process II(Proses II)

    + solution of bromine in CCl4[+ larutan bromin dalam CCl4]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    5(a)

    5(b)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    13/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    13

    (c) Draw and name the structural formula of compound P[Lukis dan namakan formula struktur sebatian P]

    [2 marks]

    (d) Describe how Process III could be done in a laboratory.

    [Perihalkan bagaimana Proses III dapat dijalankan dalam makmal]

    ........................................................................................................................................

    ........................................................................................................................................

    ........................................................................................................................................

    [3 marks]

    (e) Compound Y reacts with glacial ethanoic acid to form a sweet smelling liquid.[Sebatian Y bertindak balas dengan asid etanoik glacial membentuk larutan berbau manis]

    (i) Name the process that occured.[Namakan proses yang berlaku]

    [1 mark]

    (ii) Write a chemical equation for the above reaction.[Tuliskan persamaan kimia untuk tindak balas di atas]

    ............................................................................................................................

    [2 marks]

    Name of compound P : ...............................................................................(Namakan sebatian P)

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    5(c

    5(d

    5(e)(i)

    5(e)(ii)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    14/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    14

    6 In an experiment to study the heat of neutralization, 25.0 cm3

    of a 1.0 mol dm-3

    sodium hydroxide solution was added to 25.0 cm3

    of a 1.0 mol dm-3

    aqueous

    hydrochloric acid. The mixture was then stirred and the maximum temperature was

    recorded.

    Diagram 6 shows the set up of the apparatus used in the experiment.[Dalam satu eksperimen untuk mengkaji haba peneutralan, 25.0 cm

    3larutan natrium hidroksida 1.0

    mol dm-3

    telah ditambahkan ke dalam 25.0 cm3

    larutan akueus asid hidroklorik 1.0 mol dm-3

    .

    Campuran dikacau, dan suhu maksima direkodkan.

    Rajah 6 menunjukkan susunan radas yang digunakan dalam eksperimen ini]

    DIAGRAM 6RAJAH 6

    The following data was obtained.[Data berikut diperoleh]

    (a) What is meant by heat of neutralization?[Apakah yang dimaksudkan haba peneutralan?]

    ........................................................................................................................................[1 mark]

    (b) Write an ionic equation for the reaction between hydrochloric acid and sodium

    hydroxide.[Tulis persamaan ion bagi tindak balas antara asid hidroklorik dan natrium hidroksida]

    ........................................................................................................................................

    [1 mark]

    Initial temperature of sodium hydroxide solution = 28.5o

    C(Suhu awal larutan natrium hidroksida)

    Initial temperature of hydrochloric acid solution = 28.5oC

    (Suhu awal larutan asid hidroklorik)

    Maximum temperature of the mixture = 34.5oC

    (Suhu maksima campuran)

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    6(a)

    6(b)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    15/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    15

    (c) Based on the data obtained from the experiment, calculate[Berdasarkan data yang diperolehi daripada eksperimen, hitung]

    (i) the number of moles of hydrochloric acid used[ bilangan mol asid hidroklorik yang digunakan]

    [1 mark]

    (ii) the amount of heat released[kuantiti haba yang dibebaskan]

    [1 mark]

    (iii) the heat of neutralization

    [haba peneutralan]

    [1 mark]

    6(c)(i)

    6(c)(ii)

    6(c)(iii)

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    16/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    16

    (d) Draw the energy level diagram for the reaction.[Lukiskan gambar rajah aras tenaga bagi tindak balas]

    [2 marks]

    (e) (i) The heat of neutralization obtained from the experiment is less than the

    theoretical value. Give a reason.[Haba peneutralan yang diperoleh dari eksperimen kurang dari nilai teori. Berikan sebab]

    ............................................................................................................................

    ............................................................................................................................

    [1 mark]

    (ii) Suggest one step that should be taken to modify the apparatus in order to get

    a more accurate result.[Cadangkan satu langkah pengubahsuaian yang boleh dibuat ke atas radas untuk mendapat

    keputusan yang lebih tepat]

    ............................................................................................................................

    ............................................................................................................................

    [1 mark]

    (f) The experiment is repeated by doubling the volume of both hydrochloric acid and

    sodium hydroxide.

    Assuming the initial temperature is maintained, what would be the maximumtemperature of the mixture?[Eksperimen diulang dengan menggandakan isipadu kedua-dua asid hidroklorik dan natrium

    hidroksida.

    Dengan anggapan bahawa suhu awal tindak balas adalah sama, apakah suhu maksima campuran

    yang dijangkakan?]

    ........................................................................................................................................

    [1 mark]

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

    6(d)

    6 e i

    6(e)(ii)

    6(f)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    17/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    17

    Section B [Bahagian B]

    [20 marks]

    Answer any one question.Jawab mana-manasatu soalan.

    7 (a) Table 7.1 shows information on the atomic structure and the relative atomic mass

    of three elements: aluminium, carbon and oxygen.[Jadual 7.1 menunjukkan maklumat mengenai struktur atom dan jisim atom relatif bagi tiga

    unsur:, aluminium, karbon dan oksigen]

    Element[Unsur]

    Number of proton[bilangan proton]

    Number of neutron[Bilangan neutron]

    Relative atomic mass[Jisim atom relatif]

    Carbon

    (Karbon)6 6 12

    Oxygen(Oksigen)

    8 8 16

    Aluminium(Aluminium)

    13 14 27

    TABLE 7.1

    [JADUAL 7.1]

    (i) Based on Table 7.1, state the relationship between the relative atomic

    mass of an element with the number of proton and neutron of its atom.[Berdasarkan Jadual 7.1, nyatakan perkaitan antara jisim atom relatif dengan bilangan

    proton dan bilangan neutron yang dipunyai oleh suatu atom]

    [1 mark]

    (ii) Draw the electronic arrangement diagram for an ion of oxygen.[ Lukiskan rajah susunan electron bagi suatu ion yang terbentuk dari unsur oksigen]

    [2 marks]

    (iii) Aluminium and carbon react with oxygen to form aluminium oxide and

    carbon dioxide respectively. The reactions are represented by the

    following equations.[Aluminium dan karbon bertindak balas dengan oksigen membentuk aluminium oksida

    dan karbon dioksida.Tindak balas ditunjukkan dalam persamaan di bawah ]

    I. 4 Al + 3O2 2 Al2O3

    II. C + O2 CO2

    Describe how chemical bonds in aluminium oxide and carbon dioxide are

    formed.[Perihalkan bagaimana ikatan-ikatan kimia dalam aluminium oksida dan karbon

    dioksida dibentuk]

    [8 marks]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    18/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    18

    (b) Naphthalene and sodium chloride are white crystals at room temperature. Table

    7.2 shows two physical properties of the compounds.[Naftalena dan natrium klorida adalah hablur berwarna putih pada suhu bilik. Jadual 7.2

    menunjukkan dua sifat fizik bagi kedua-dua sebatian]

    Compound(Sebatian) Melting point /

    0

    C(Takat lebur) Electrical conductivity(Kekonduksian elektrik)

    Naphthalene(Naftalena) 80

    Non electrolyte(Bukan elektrolit)

    Sodium chloride

    (Natrium klorida)801

    Electrolyte(Elektrolit)

    TABLE 7.2JADUAL 7.2

    Explain the differences in the melting points and the electrical conductivity of

    naphthalene and sodium chloride.

    Your answer should be based on the[Terangkan perbezaan takat lebur dan kekonduksian elektrik bagi naftalena dan natrium

    klorida. Jawapan anda hendaklah berdasarkan kepada]

    types of particles present in both compounds[ jenis zarah yang hadir dalam kedua-dua sebatian]

    types of bonds and[jenis ikatan]

    forces of attraction[daya tarikan antara zarah]

    [5 marks]

    (c) Diagram 7 shows the symbol of two atoms of oxygen.[Rajah 7 menunjukkan simbol bagi dua atom oksigen]

    DIAGRAM 7RAJAH 7

    Compare and contrast the two atoms of oxygen.[Banding dan bezakan kedua-dua atom oksigen ini]

    [4 marks]

    O18

    8O16

    8

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    19/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    19

    8 (a) Table 8 shows the pH of two solutions.[Jadual 8 menunjukkan pH bagi dua larutan]

    Solution pH

    0.1mol dm-3 of potassium hydroxide solution(Larutan kalium hidroksida 0.1 mol dm-3 ) 130.1mol dm-3 of aqueous ammonia(Larutan ammonia 0.1 mol dm

    -3)

    11

    TABLE 8[JADUAL 8]

    Explain why the two solutions have different pH.[Terangkan mengapa kedua-dua larutan mempunyai nilai pH yang berbeza.].

    [4 marks]

    (b) An unlabeled reagent bottle is said to contain sulphuric acid solution.

    Describe how you would confirm the solution.[Satu botol reagen yang tidak berlabel dikatakan mengandungi larutan asid sulfurik.

    Perihalkan bagaimana anda mengesahkan larutan itu]

    [4 marks]

    (c) The structural formula of ethanoic acid is shown in Diagram 8.[Formula struktur bagi asid etanoik ditunjukkan dalam Rajah 8]

    DIAGRAM 8[RAJAH 8]

    (i) Explain why ethanoic acid is a monoprotic acid.

    [ Terangkan mengapa asid etanoik adalah asid monobes]

    [2 marks]

    (ii) Glacial ethanoic acid does not conduct electricity but the aqueous solution

    of ethanoic acid does. Explain why.[Asid etanoik glasial tidak mengkonduksikan elektrik tetapi larutan akueus asidetanoik mengkonduksikan elektrik. Terangkan mengapa]

    [3 marks]

    (iii) When zinc powder is added into an aqueous ethanoic acid, bubbles of

    colourless gas are evolved.

    Write a chemical equation for the reaction.[Bila serbuk zink ditambahkan ke dalam larutan akueus asid etanoik, gelembung-

    gelembung gas tidak berwarna dibebaskan.

    Tuliskan persaman kimia bagi tindak balas ini]

    [2 marks]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    20/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    20

    (d) The equation below shows the reaction between hydrochloric acid and

    magnesium.[Persamaan di bawah menunjukkan tindak balas antara asid hidroklorik dan magnesium]

    Mg + 2HCl MgCl2 + H2

    50.0 cm3

    of hydrochloric acid solution reacts with excess magnesium to produce

    48 cm3

    of hydrogen gas.

    Calculate the concentration of the hydrochloric acid used.

    [Molar volume of gas = 24.0 dm3

    mol-1

    ][Satu larutan 50.0 cm

    3asid hidroklorik bertindak balas dengan magnesium yang berlebihan

    menghasilkan 48 cm3 gas hydrogen.

    Hitungkan kepekatan asid hidroklorik]

    [3 marks]

    (e) Emission of gaseous pollutant from vehicles and industries leads to the

    formation of acid rain.

    Explain the effect of acid rain to the structure of buildings.[Pelepasan gas-gas pencemar dari kenderaan dan industri boleh menghasilkan hujan asid.

    Terangkan kesan hujan asid terhadap struktur bangunan.]

    [2 marks]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    21/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    21

    Section C( Bahagian C)

    [20 marks]

    Answer any one question.Jawab mana-manasatu soalan.

    9 (a) The following equations represent two chemical reactions,[Berikut adalah persamaan-persamaan bagi dua tindak balas kimia.]

    I. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3 (aq)

    II. Zn(s) + CuSO4(aq) ZnSO4 (aq) + Cu (s)

    Based on the equations, determine whether the reaction is a redox reaction.

    Explain your answer.[Berdasarkan kepada persamaan kimia ini tentukan sama ada setiap tindak balas adalah

    tindak balas redoks atau bukan.

    Terangkan jawapan anda ]

    [4 marks]

    (b) Diagram 9 shows a cross section of two iron bars, P and Q which are plated by

    zinc and tin layers respectively.[Rajah 9 menunjukkan keratan rentas bagi dua batang besi, P dan Q yang masing-masing disadur

    dengan lapisan zink dan stanum]

    DIAGRAM 9RAJAH 9

    Explain how zinc and tin layers in P and Q protect the iron bars from corrosion.

    Determine which iron bar is more protected from corrosion.[Terangkan bagaimana lapisan-lapisan zink dan stanum dalam P dan Q melindungi besi dari

    kakisan.

    Tentukan batang besi yang manakah lebih dilindungi dari kakisan]

    [ 6 marks]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    22/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    22

    (c) Fe2+

    ion can be oxidized to Fe3+

    ion while Fe3+

    ion can be reduced to Fe2+

    ion

    as shown in the following half-equations.[Ion Fe2+ boleh dioksidakan kepada ion Fe3+ manakala ion Fe3+ boleh diturunkan kepada

    ion Fe2+ seperti ditunjukkan dalam setengah persamaan berikut.

    Fe2+

    Fe3+

    + e

    Fe3+

    + e Fe2+

    Design an experiment to show how these two changes can be carried out.

    Your answer should consist of the following:[Reka bentuk satu eksperimen bagi menunjukkan bagaimana dua perubahan ini dapat

    dijalankan. Jawapan anda harus mengandungi perkara berikut]:

    Chemicals required[Bahan kimia yang diperlukan]

    Procedure of the experiment[Prosedur eksperimen]

    Observation[Pemerhatian]

    Overall chemical equation involved in the reaction[Persamaan tindak balas keseluruhan]

    [10 marks]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    23/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    23

    10 Sodium stearate and sodium dodecyl sulphate are cleaning agents. Their molecular formulae

    are shown in Diagram 10.1.[Natrium stearat dan natrium dodekil sulfat adalah agen pembersihan. Formula molekul mereka ditunjukkan

    dalam Rajah 10.1].

    DIAGRAM 10.1RAJAH 10.1

    (a) (i) Sodium stearate dissolves in water to form ions. Write an equation to show

    the ionization of sodium stearate.[Natrium stearat larut dalam air membentuk ion. Tuliskan persamaan untuk

    menunjukkan pengionan natrium stearat]

    [1 mark]

    (ii) Determine which of the two cleaning agents is more effective in their

    cleansing action in hard water. Give reasons.[Tentukan agen pembersihan yang mana satukah lebih berkesan dalam tindakan pencucian

    dalam air liat. Berikan alasan]

    [4 marks]

    (iii) Fat reacts with an alkali to form soap.

    Describe an experiment to prepare a sample of soap. Your answer should

    include:[Lemak bertindak balas dengan alkali membentuk sabun.

    Perihalkan satu eksperimen untuk menyediakan satu sampel sabun. Jawapan anda harus

    mengandungi]

    Chemicals used[Bahan kimia yang diperlukan]

    Procedure[Prosedur]

    A test to verify the soap sample that you have prepared hasa cleansing effect.[Satu ujian untuk mengesahkan sampel sabun yang anda sediakan

    mempunyai kesan pembersihan]

    [8 marks]

    Sodium stearate : CH3(CH2)16COONa(Natrium stearat)

    Sodium dodecyl sulphate : CH3(CH2)11OSO3Na(Natrium dodekil sulfat)

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    24/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    24

    (b) Diagram 10.2 shows the arrangement of atoms of two substances, X and Y in solid

    state.[Rajah 10.2 menunjukkan susunan atom-atom dalam dua bahan X dan Y pada keadaan pepejal]

    X Y

    DIAGRAM 10.2RAJAH 10.2

    Based on Diagram 10.2, differentiate the arrangement of atoms and the

    properties of substance X and Y.[Berdasarkan Rrajah 10.2, bezakan susunan atom dan sifat-sifat bagi bahan X dan Y]

    [7 marks]

    END OF QUESTION PAPERKERTAS SOALAN TAMAT

    Tin atom[Atom stanum]

    Copper atom[Atom kuprum]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    25/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    25

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN: ......................... QUESTION NO. / NO. SOALAN: ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    26/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    26

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN: ......................... QUESTION NO. / NO. SOALAN: ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    27/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    27

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN : ......................... QUESTION NO. / NO. SOALAN: ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    28/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    28

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN: ......................... QUESTION NO. / NO. SOALAN : ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use

    [Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    29/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    29

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN: ......................... QUESTION NO. /NO. SOALAN: ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    30/31

    CONFIDENTIAL 4541/2

    4541/ 2 CONFIDENTIAL

    30

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN : ......................... QUESTION NO. / NO. SOALAN : ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]

  • 8/14/2019 SPM Percubaan 2007 MRSM Chemistry Paper 2

    31/31

    CONFIDENTIAL 4541/231

    SPACE FOR YOUR ANSWER / RUANG JAWAPAN

    SECTION / BAHAGIAN : ......................... QUESTION NO. /NO. SOALAN : ............

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    __________________________________________________________________________

    For

    Examiners

    Use[Untuk

    Kegunaan

    Pemeriksa]