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    EAT 106: Thermodynamics & Fluid

    Mechanics

    Lecture 1

    Introduction and basic concepts

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    Chapter Overview

    Units system.

    System, state, state postulate, equilibrium,

    and process.

    Temperature, and temperature scale.

    Pressure: absolute and gage pressure.

    Manometer and barometer.

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    Thermodynamics and energy

    Thermodynamics science of energy,

    macroscopic approach, classical

    thermodynamics.

    Energy is the ability to cause changes.

    Thermodynamics: Heat => power (Greek).

    Today, all aspect of energy and itstransformation.

    Law: Conservation of energy.

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    Thermodynamics and energy

    Conservation of energy:

    Energy can change from one form to

    another but the total amount of energy

    remains constant, it cannot be created or

    destroyed.Energy in (food)

    5 units

    Energy storage4.5 units

    Energy out0.5 units

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    Thermodynamics and energy

    The change of energy content of a body or any other

    system is equal to the difference between the energy

    input and the energy output.

    Energy balance: Ein

    Eout=E

    Energy in (food)

    5 units

    Energy storage4.5 units

    Energy out0.5 units

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    Thermodynamics and energy - (1850s)

    1st law of thermodynamics: conservation of energy,

    energy is a thermodynamic property.

    2nd

    law of thermodynamics: energy has quality, andquantity, actual processes occurs in the direction of

    decreasing quality of energy.

    Heat out

    Cool coffee in the same room never getshot by itself. The high temperature energy

    of the coffee is degraded, as the energy is

    transferred to the surrounding air.

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    Area of application

    The warming ofhuman body: a balancebetween metabolism and heat rejection.

    Household: heating and air-conditioningsystems, refrigerator, pressure cooker, waterheater, computer.

    Industry: rockets, jet engine, conventional ornuclear power plants, solar collectors, thedesign from cars to airplanes.

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    Dimensions

    For a given dimension such as length can be

    expressed in a number of different units such as

    meters, millimeters, or kilometers.

    DIMENSIONS is different from a unit. The principle of dimensional homogeneity states

    that all physical relations must be dimensionally

    homogeneous.

    Based on L, M, and T.

    Force is a derived quantity in SI units: F = MLT-2

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    Dimensions and Units

    Four primary dimensions of mechanics:

    Quantity Dimensional

    Symbol

    SI Units

    Unit SymbolMass M Kilogram kg

    Length L Meter m

    Time T Second s

    Force F Newton N

    Derived dimension: velocity and acceleration: ms-1, and ms-2.

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    Dimensions

    One important use of the dimensional homogeneityprinciple is to check the dimensional correctness ofsome derived physical relation.

    Dimensional homogeneity is a necessary condition forcorrectness of a physical relation, but is not sufficient.

    It is possible to construct an equation which isdimensionally correct but does not represent a correctrelation.

    2122

    ]][[]][[2

    1 LTMLMLTmvxF

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    Gravitation

    Newtons law of gravitation:

    F: the mutual force of attraction between two particles.

    G: a universal constant called the constant of gravitation,

    6.673(10-11) m3kg-1s-2.

    m1, m2: the masses of the two particles r: the distance between the centers of the particles

    2

    21

    r

    mmGF

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    Gravitation

    Newtons law of gravitation:

    2

    2

    2

    21

    81.9:

    msgWhere

    mgWeightmR

    mGF

    r

    mmGF

    particleparticleE

    me: mass of earth, 5.976(1024) kg;R: 6.371(106) m

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    Weight and Mass

    The mass of a body remains the same

    regardless of its location in the universe.

    The weight changes with a change in

    gravitational acceleration.

    A body weighs less on a mountain asg

    decreases, and it is 1/6lesser on the moon.

    Vm

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    System and Control Volumes

    System is defined as a quantity of matteror a region in space chosen for study.

    Boundary can be real or imaginary, fixedor moveable, zero thickness (no mass andvolume).

    System

    Surroundings

    Boundary

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    System and Control Volumes

    Closed system: mass is fixed, no mass can cross the

    boundary; energy can as heat and work; the volume

    does not has to be fixed.

    Isolated system: closed system + no energy allow tocross the boundary.

    Closed system

    m = constant

    Energy

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    System and Control Volumes

    Piston and cylinder.

    Gas, 2 kg, 1m3

    Heating

    Closed system

    Boundary

    Surrounding

    Gas, 2 kg, 2m3

    Closed system

    Moving boundary

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    System and Control Volumes

    Open system: both mass and energy can

    cross the boundary of the system.

    Water heater, turbine, compressor

    involve mass flow, thus a open system.

    Nozzle

    Real Boundary

    Imaginary

    Boundary

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    System and Control Volumes

    The boundaries of an open system are

    called control surface.

    Moving

    boundary

    Fixed

    boundaryFlow in

    Flow in

    Flow out

    Water Heater

    How much

    heat is

    needed to

    maintain asteady

    stream of

    hot water?

    Control surface

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    Properties of a System

    Any characteristic of a system is called a property.

    PressureP, temperature T, Volume V, and mass m.

    Viscosity, thermal conductivity, modulus of elasticity,thermal expansion coefficient, electric resistively, velocityand elevation

    Intensive properties: independent of massP, T,

    density; uppercase. Extensive properties: depend on mass mass,

    volume; lowercase. Specific propertis: v=V/m, e=E/m.

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    Continuum

    Matter is made up of atoms.

    Size of the system deal is large relative to the

    space between molecules.

    Mean free path: distance travels before the nextcollision, O2 at 1 atm 20

    oCis 6.3x10-8 m.

    The substance can be viewed as continuous,

    homogeneous matter with no holes. The density of water is the same at any point.

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    Density and Specific Gravity

    Density: mass per unit volume.

    The reciprocal of density: specific volume.

    Density is a function of temperature and

    pressure. Liquids and solids are incompressible, thus only

    depend on temperature.

    Specific gravity: the ratio of the density of a

    substance to the density of some standardsubstance at a specified temperature.

    COH o

    SG4,2

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    Density and Specific Gravity

    SG < 1, will float on water.

    Specific weight: weight per unit volume.

    g

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    State and Equilibrium

    If a system does not undergoing any

    change, all the properties can be

    measured and completely describe the

    condition, or the state of the system.

    At a given state, all the properties have

    fixed values.

    2kg, 20oC,

    1.5m3

    2kg, 20oC,

    2.5m3

    State 1 State 2

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    State and Equilibrium

    Thermodynamics deals equilibrium state.

    Equilibrium implies a state of balance.

    There are many types of equilibrium. A system is not in

    thermodynamic equilibrium unless the conditions of all the relevanttypes of equilibrium are satisfied.

    Thermal equilibrium: temperature are the same throughout the entiresystem.

    Mechanical equilibrium: pressure are the same.

    Phase equilibrium: the mass of each phase reach equilibrium andwill not change.

    Chemical equilibrium: chemical composition will not change withtime.

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    State and Equilibrium

    The state of a system is described by itsproperties.

    We do not need to specify all the properties to fixa state.

    Once a sufficient number of properties arespecified, the rest of the properties assumecertain value automatically.

    The number of properties required to fix the

    state is given by the state postulate. A simple compressible system: temperature, and

    specific volume. Thus 2 independent intensityproperties.

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    Processes and Cycles

    Any change that a system undergoes from one

    equilibrium state to another is called a process.

    The series of state a system passes during the

    process is called the path.

    State 1

    State 2

    Process path

    Property A

    Property B

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    Processes and Cycles

    Process proceed in a manner that the system remain infinitesimallyclose to an equilibrium state at all the times, quasi-static, orquasi-equilibriumprocess.

    A sufficiently slow process that allows the system to adjust itself

    internally so that properties in one part of the system do not changeany faster than those at other parts.

    Slow compression

    Fast compression

    Uniform pressure, and

    raise at same rate

    Non-uniform

    pressure

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    Processes and Cycles

    Final state

    Initial state

    P

    V

    System

    Quasi-equilibriumprocess

    Non-quasi-equilibrium process

    Isothermal process: aprocess during whichtemperature remainsconstant.

    Isobaric process:

    pressure remainsconstant.

    Isochoric process:specific volume remainsconstant.

    A system is said to have undergone a cycle if it returns to its initial stateat the end of the process. The initial and final states are identical.

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    The Steady-Flow Process

    Steady: no change with time.

    Thus, the opposite is unsteady and transient.

    Uniform: no change with location over a specified region.

    Under steady-flow conditions, the mass and energy contents of a control

    volume remain constant.

    Mass in

    Mass out

    300oC 250oC

    200oC 150oC

    Time: 1 pm

    Mass in

    Mass out

    300oC 250oC

    200oC 150oC

    Time: 3 pm

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    Temperature and the Zeroth Law of Thermodynamics

    Zeroth law of thermodynamics (Fowler,

    1931): if two bodies are in thermal

    equilibrium with a third body, they are also

    in thermal equilibrium with each other.

    The temperature are the same.

    K (Kelvin), SI temperature unit.

    T(K) = T(oC) + 273.15

    T(K) =T(oC)

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    Pressure

    Pressure: normal force exerted by a fluid

    per unit area.

    When dealing with gas or liquid.

    For solid: normal stress.

    Unit: 1 N/m2 = 1 Pascal, Pa.

    1 bar = 105

    PaP = F/A

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    Pressure

    Absolute pressure, is a measure relative to

    absolute vacuum (i.e. absolution zero pressure).

    Most pressure-measuring device are calibrated

    to read zero in the atmospheric pressure thegage pressure.

    Pressure below atmospheric pressure is called

    vacuum pressure.

    Absolute, gage and vacuum pressures are all

    positive quantities.

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    Pressure

    Pgage = PabsPatm

    Pvac = PatmPabs

    In thermodynamics relations and tables,absolute pressure is almost always used.

    Pwill denote absolute pressure unless

    specified otherwise.

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    Pressure

    Patm

    Patm Patm

    Pabs Pabs

    Pvac

    Pgage

    Pabs= 0Absolute vacuum

    Pressure is a compressive force

    per unit area, scalar quantity.

    Pressure at any point in a fluid is

    the same in all directions.

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    Example

    A vacuum gage connected to a chamber

    reads 40 kPa at a location where the

    atmospheric pressure is 100 kPa.

    Determine the absolute pressure in thechamber.

    Pabs = PatmPvac = 100 40 = 60 kPa

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    Variation of Pressure with Depth

    Pgage The pressure in a fluid at rest does not

    change in the horizontal direction.

    The pressure in a fluid at rest increases

    with depth as a result of added weight.

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    Variation of Pressure with Depth

    z

    x

    W

    P1

    P2

    0 x

    z

    Unit depth (into the page), y = 1

    Assuming the density of fluid, = constant

    The force balance in thezdirection,

    zPPP

    zgPPP

    zgPP

    zxgxPxPmaF

    s

    zz

    12

    12

    12

    12

    0

    0

    :0

    s is the specific weight.

    Pressure head

    Free body diagram of a rectangular

    fluid element in equilibrium

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    Variation of Pressure with Depth

    1

    h

    P1 = Patm

    P2 = Patm+gh

    Liquids are incompressible, the variation ofdensity of negligible.

    For small elevation change the gas densitycan be neglected.

    Temperature will change with fluids.

    For ocean and large elevation,

    2

    112 gdzPPP

    2

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    The Basic Barometer

    h

    The measure the atmospheric pressure.

    Patm = gh, Hg = 13595 kgm-3

    h = 760 mm = 1 atm, standard atmosphere.

    At 0oC and g = 9.807 ms-2,W

    PaP

    ghP

    APghAW

    atm

    atm

    atm

    9.101327

    Patm

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    Example: Manometer

    A manometer is used to measure the pressure in a tank. The fluid used has

    a specific gravity of 0.85, and the manometer column height is 55 cm, as

    shown in the figure. If the local atmospheric pressure is 96 kPa, determine

    the absolute pressure within the tank.

    h = 55cm

    Patm = 96 kPa

    SG = 0.85

    P = ?

    Assumption:

    The fluid in the tank is a gas whose density is

    much lower than the density of manometer fluid

    The gravitational effect of the gas is negligible,

    the pressure anywhere in the tank and the

    position 1 are the same.

    kPaP

    P

    ghPPkgmSG

    atm

    OH

    6.100

    )55.0)(81.9(85096

    850100085.0

    3

    2

    1

    2

    3

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    Manometer: Pressure Drop Measurement

    ghPP

    ghghPP

    gaghPhagP

    PP BA

    1221

    1221

    12211

    h

    Fluid

    1 2

    A flow section or flow device

    1

    2

    AB

    a

    Horizontal device.

    Valve, heat exchanger, or any

    resistance to flow.

    a has not effect on the result.

    If1

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    Example: Effect of piston weight on pressure in a cylinder

    The piston of a vertical piston-cylinder device containing a gas has mass of

    60 kg and a cross-sectional area of 0.04m2. The local atmospheric pressure

    is 0.97 bar, and the gravitational acceleration is 9.81ms-2. (a) Determine the

    pressure inside the cylinder. (b) If some heat is transferred to the gas and

    its volume is doubled, do you expect the pressure inside the cylinder to

    change?

    A = 0.04m2

    Patm = 0.97 bar

    m = 60 kg

    Assumption: Friction between the

    piston and the cylinder is negligible.Patm

    W =mg barP

    P

    A

    W

    PP

    WAPPA

    atm

    atm

    12.1

    1004.0

    81.96097.0

    5

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    Example: Effect of piston weight on pressure in a cylinder

    The piston of a vertical piston-cylinder device containing a gas has mass of

    60 kg and a cross-sectional area of 0.04m2. The local atmospheric pressure

    is 0.97 bar, and the gravitational acceleration is 9.81ms-2. (a) Determine the

    pressure inside the cylinder. (b) If some heat is transferred to the gas and

    its volume is doubled, do you expect the pressure inside the cylinder to

    change?

    The volume change will have no effect on the free-body diagram,

    therefore the pressure inside the cylinder will remain the same.

    If the gas behaves as an ideal gas, the absolute temperature doubles

    when the volume is doubled at constant pressure.