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    Luluhawa batuan mendak

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    Learning objectives

    luluhawa

    1 Apa itu

    2 Bagaimana

    terjadi

    3 Jenis2 luluhawa4 Faktor2 yg mempengaruhi

    luluhawa

    5 Impak/kesan

    6 hasil

    7 kepentingan

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    Luluhawa suatu proses yang

    berlaku di permukaan bumi untukmemecah dan menguraikan

    batuan (break and decompose

    rocks)Enviromen: terhad kepada sejauh

    mana air tanah (groundwater)boleh menusuk masuk (penetrate)

    ke dalam permukaan bumi

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    luluhawa

    Boleh dilihat sebagai destructive forces

    - yang memecah, mengurai, mengubah

    bentuk dan keadaan fizikal dan kimia batuan Boleh dilihat sebagai constructive forces

    yang menghasilkan sedimen, membentuk

    batuan mendak, mineral, mendapanmineral, landform baru

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    Jenis2 luluhawa

    1. Luluhawa fizikal

    2. Luluhawa kimia

    3. Luluhawa biologi

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    1. Luluhawa fizikal

    Memecahkan batuan yang bersaiz besar kepadabahagian yang lebih kecil

    contoh: wedging (pembajian), exfoliation(pengelupasan), thermal expansion (kembanghaba), lelasan (abrasion), (wetting and drying (espin shales), pressure release by erosion ofoverburden

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    Luluhawa fizikal

    1 Frost wedging (pembajian ibun) water

    expands when it freezes, breaking rocks

    into angular fragments; lazim berlaku

    dalam iklim temperat (ada ais)

    Nota: apabila air menjadi ais, isipadu

    meningkat sebanyak 10% => mebungkah

    (pries) batuan

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    talus terdapat di kaki bukit

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    Luluhawa fizikal

    2 Exfoliation (pengelupasan) bedrocks

    (batuan hampar) breaks into flat sheets

    along joints (kekar) which parallel the

    ground surface. This phenomenon is

    caused by expansion of rock when the

    pressure of overlying rock is removed by

    erosion => sometimes called unloading

    Apa itu kekar?

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    Exfoliation Stone Mt

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    exfoliation

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    exfoliation

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    Active exfoliation Stone Mt

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    goblin

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    Mt Kinabalu

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    Mt Kinabalu

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    Mt Kinabalu

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    4 Lelasan (abrasion)

    Batuan menjadi lebih kecil hasi drpd

    pergeseran dan pelanggaran semasa

    terangkut, contohnya di dasar sungai

    Glasial, ombak dan angin juga boleh

    menjadi agen lelasan

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    Kelebihan kimia fizikal

    Luluhawa fizikal memecahkan batuan ke

    saiz yg lebih kecil => menyediakan lebih

    banyak luas permukaan batuan bersaiz

    kecil untuk tindakbalas kimia berlaku

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    2. Luluhawa kimia

    Memecahkan batuan secara kimia dgn

    menambah atau menanggalkan (removing)

    unsur2 kimia, mengubah unsur2 tersebut

    menjadi bahan2 baru

    contoh: dissolution (pelarutan), hydrolysis

    (hidrolisis), oxidation (pengoksidaan)

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    Luluhawa kimia

    1 Dissollution (pelarutan) alters rocks by

    removing soluble minerals => soluble ions

    and insoluble ions => precipitate and

    crystallize (dalam tasik atau laut)

    Ex: pembentukan garam, batu kapur,

    travertine

    Batuan => ion larut/ tak larut => pemendakan

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    Luluhawa fizikal

    3 Thermal expansion (kembang haba) heat

    causes action; cooling causes contraction

    => expand and contract at different rate

    causes stresses along mineral boundaries.

    Repeated heating and cooling => batuan

    pecah

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    Luluhawa kimia

    2 Hydrolisis proses di mana feldspar are

    weathered to form clay

    Note: clay make up half of sedimentaryrocks on Earth

    (Berapa jenis feldspar kita ada? Apakahkomposisinya?)

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    Weathering of feldspar

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    Beberapa contoh t/b kimia

    A. Solution of carbon dioxide in water to form

    acid

    CO2 + H2O H2CO3 H

    +

    + HCO3-

    B. Solution of calcite

    CaCO3 + CO2 + H2O Ca2+ + 2HCO3

    -

    C. CaCO3 + H+ HCO3

    - Ca2+ + 2HCO3-

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    D. Chemical weathering of feldspar to form

    clay mineral

    2KAlSi3O8 + 2H

    +

    + 2HCO3-

    + H2OK feldspar

    Al2Si2O5(OH)4 + 2K+ + 2HCO3

    - + 4SiO2

    clay mineral Silica in solutionor as fine solid

    particles

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    2KAlSi3O8

    Al2Si

    2O

    5(OH)

    4

    K2O

    Al2O36SiO2

    Al2O3

    2SiO22H2O

    Cara jurutera bahan mengungkap formula

    untuk memudahkan kefahaman

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    Luluhawa kimia

    3 oxidation the process by which iron-

    bearing minerals (pyroxene, amphibole,

    biotite) weather to produce iron oxides

    Di kawasan tropik iron bearing

    aluminosilicate => lateritic soils, red clayey

    soils

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    Oxidation reaction

    4FeSiO3 + O2 +10H2O 4FeO.OH +

    4H4SiO4

    2Fe2SiO4 + 2O2 + 4H2O 4FeO.OH +

    2H4

    SiO4

    Fe pyroxene

    Fe olivine

    Goetite

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    3. Luluhawa biologi

    Pemecahan batuan disebabkan oleh

    tindakan organisma hidup spt tumbuh2an,

    haiwan dalam tanah dan lichen (kulat? yang

    hidup di atas batuan dan kayu)

    Pengaruh => minimum

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    Hasil luluhawa

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    Weathering products

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    Average daily temperatures range from aminimum of 25o C to a maximum of 33o C.

    has an average annual rainfall of morethan 2500 mm

    Malaysia

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    Hujan dan suhu

    driest

    wettest

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    Mineral stability in the weathering

    environment

    Mineral didapati tak stabil dalam enviromentertentu

    Minerals which formed at high temperatureand pressures are least stable in theweathering environment and weather mostquickly

    Minerals which formed at lower temperaturesand pressures are most stable underweathering conditions

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    Rates of weathering

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    Soil profile

    D horizon

    Fresh rocks

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    Soil profile

    Eluviation

    illuviation

    leaching

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    Leaching/larutlesap: proses kimia yangmenghasilkan unsur larut dan tak larut.

    Yang larut akan lesap ke bawah dalamprofil tanah sementara yang tak larut akanterkumpul di bahagian atas profil tanah =>warna membezakan lapisan tanah

    Eluviation: removal of materials dissolvedor suspended in water

    Illuviation: horizon of maximum

    accumulation of suspended material orclay

    Chelation: pembentukan kompleks kimia

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    Laterite profile

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    Acid run-off at gold mine

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    bryce

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    Oxidation effect

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    Oxidation effects

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    Staglatite-staglamite

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    sinkholes

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    Sinkholes (tanah benam)

    Bagaimana terjadi?

    Enviromental problem?

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    Jenis2 tanah

    Residual soil - laterit, iklim tropik

    Transported soil till, loess, iklim temperat

    Tanih - pelbagai jenis tanah

    contoh: laterit, pedalfer, latosol,

    paleosol

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    Wentworth scale - grain size scale Particle name Particle diameter Gravel

    Boulders > 256 mm

    Cobbles 64 - 256 mm

    Pebbles 2 - 64 mm

    Granules 2 - 4 mm

    Sand

    Very coarse sand 1 - 2 mm Coarse sand 0.5 - 1 mm

    Medium sand 0.25 - 0.5 mm

    Fine sand 0.125 - 0.25 mm

    Very fine sand 0.0625 - 0.125 mm Silt 1/256 - 1/16 mm

    (or 0.004 - 0.0625 mm)

    Clay < 1/256 mm(or < 0.004 mm) sesetengah

    buku guna takrif

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    Kitar batuan (Rock cycle)

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    Hakisan (erosion)

    The movement of weathered material from

    the site of weathering. Primary agent is

    gravity, but gravity acts in concert with

    running water

    pergerakan bahan terluluhawa dari tempat

    luluhawa berlaku ke tempat ia ditemui

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    Sedimentary cycle

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    Malaysia bagaimana?

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    Faktor yang mempengaruhi

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    Faktor yang mempengaruhi

    pembentukan tanah

    1. Iklim (climate)

    2. Batuan induk (parent material)

    3. Relief (keadaan permukaan bumi)

    4. Vegetation (tumbuhan)

    5. Masa (time)

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    Sambung => batuan mendak

    (lihat beberapa transparensimengenai luluhawa)

    Apa kesudahannya?

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    Batuanmendak

    apa

    Bagaimanaterjadi

    Perubahan sebelum, semasa dan

    selepas pembentukan

    jenis2

    kepentingan

    Apa kesudahannya?

    Ciri2 utama Di mana

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    Sediment = loose particulate material (clay,

    sand, silt, gravel, etc.)

    Sediment becomes sedimentary rock

    through lithification, which involves:

    Compaction

    Cementation

    Recrystallization (of carbonate sediment)

    Hasil drpd luluhawa ialah sedimen

    W t th l i i l

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    Wentworth scale - grain size scale Particle name Particle diameter Gravel

    Boulders > 256 mm Cobbles 64 - 256 mm

    Pebbles 2 - 64 mm

    Granules 2 - 4 mm

    Sand

    Very coarse sand 1 - 2 mm Coarse sand 0.5 - 1 mm

    Medium sand 0.25 - 0.5 mm

    Fine sand 0.125 - 0.25 mm

    Very fine sand 0.0625 - 0.125 mm Silt 1/256 - 1/16 mm

    (or 0.004 - 0.0625 mm)

    Clay < 1/256 mm(or < 0.004 mm) sesetengah

    buku guna takrif

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    Ternary diagram Sand-Silt-Clay

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    Kitar batuan (Rock cycle)

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    Classification of sedimentary rocks

    Hjulstrom Curve

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    Hjulstrom Curve

    Menghubungkait vel-size dgn proses (1939)

    A Terrigenous (also called detrital or clastic)

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    A. Terrigenous (also called detrital or clastic)

    Terrigenous sedimentary rocks are derived fromthe weathering of pre-existing rocks, which havebeen transported to the depositional basin. Theyhave a clastic (broken or fragmental) textureconsisting of:

    1.Clasts (larger pieces, such as sand or gravel)

    2.Matrix (mud or fine-grained sedimentsurrounding the clasts)

    3.Cement (the glue that holds it all together), suchas:

    1.calcite2.iron oxide

    3.silica

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    Clasts and

    matr ix

    (labelled),and i ron oxide

    cement

    (redd ish brownco lor)

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    Sand: Grain size 1/16 to 2 mm

    Sandstone

    If dominated by quartz grains = quartz

    sandstone (also called quartz arenite)

    If dominated by feldspar grains = arkose

    If dominated by sand-sized rock fragmentgrains = lithic sandstone (also called

    litharenite orgraywacke)

    l t

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    conglomerate

    b i

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    breccia

    Q t d t

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    Quartz sandstone

    Arkose (mengandungi banyak feldspar)

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    Arkose (mengandungi banyak feldspar)

    Greywacke (sand-sized rock

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    Greywacke (sand sized rock

    fragments)

    S G / / ( )

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    Silt: Grain size 1/256 to 1/16 mm (gritty)

    Siltstone

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    Clay: Grain size less than 1/256 mm

    (smooth) (< 2 micron)

    Shale (if fissile)

    Claystone (if massive)

    Note: Mud is technically a mixture of silt and

    clay. It forms a rock called mudstone (or

    mudshale if fissile).

    h l

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    shale

    k li

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    kaolin

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    B. Chemical/biochemical Sedimentary

    Rocks

    This group includes the evaporites, the

    carbonates (limestones and dolostone),and the siliceous rocks. These rocks form

    within the depositional basin from chemical

    components dissolved in the seawater

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    Evaporites - The evaporites form from theevaporation of water (usually seawater).

    Rock salt - composed of halite (NaCl).

    Rock gypsum - composed of gypsum

    (CaSO4.2H20) Travertine - composed of calcium

    carbonate (CaCO3), and therefore, also

    technically a carbonate rock; travertineforms in caves and around hot springs.

    Bonneville Salt Flats of the Great Salt Lake, Utah. The lake

    bed is covered with rock salt which gives it the white color

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    bed is covered with rock salt which gives it the white color.

    The salt is mined by the Morton Salt Company.

    gypsum

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    gypsum

    Gypsum crystals, Marion lake,

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    yp y , ,

    Australia

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    Carbonate rock names:

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    Micrite (microcrystalline limestone) - very fine-grained; may be light gray or tan to nearly black in

    color. Made of lime mud, which is also calledcalcilutite.

    Oolitic limestone (look for the sand-sized oolites)

    Fossiliferous limestone (look for various types offossils in a limestone matrix)

    Coquina (fossil hash cemented together; mayresemble granola)

    Chalk (made of microscopic planktonic organismssuch as coccolithophores; fizzes readily in acid)

    Crystalline limestone

    Travertine (see evaporites)

    Others - intraclastic limestone, pelleted limestone

    Stromatolitic limestone

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    Stromatolitic limestone

    Batuan karbonat di Mexico

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    Batuan karbonat di Mexico

    Siliceous rocks - The siliceous rocks are thosewhich are dominated by silica (SiO2) They

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    which are dominated by silica (SiO2). Theycommonly form from silica-secreting organisms

    such as diatoms, radiolarians, or some types ofsponges. Chert is formed through chemicalreactions of silica in solution replacinglimestones.

    Diatomite - looks like chalk, but does not fizz inacid. Made of microscopic planktonic organismscalled diatoms. May also resemble kaolinite, butis much lower in density and more porous).

    Also referred to as Diatomaceous Earth. Chert - Massive and hard, microcrystalline

    quartz. May be dark or light in color. Oftenreplaces limestone. Does not fizz in acid.

    . Organic Sedimentary Rocks (Coals)

    This group consists of rocks composed of organic

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    This group consists of rocks composed of organicmatter (mainlyplant fragments). Because of this, theylack minerals (which must be inorganic, be definition).

    These are the coals. In order of increasing depth ofburial (temperature and pressure):

    Peat (porous mass of brownish plant fragmentsresembling peat moss)

    Lignite (crumbly and black) Bituminous coal (dull to shiny and black; sooty;

    layers may be visible)

    Anthracite coal (extremely shiny and black, may

    have a slight golden shine; low density; not sooty;technically a metamorphic rock due to hightemperatures and pressures to which it has beensubjected)

    others

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    others

    There are several other interesting

    sedimentary rock types: Ironstones -Oolitic hematite, banded iron formations

    Abundance of sedimentary rocks

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    Abundance of sedimentary rocks

    Soalan

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    Soalan

    Maklumat apakah yang boleh dicerap dari

    pemerhatian batuan mendak?

    Senaraikan

    Sedimentary Structures

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    Sedimentary structures form in the basin of

    deposition, as a result of the action ofnatural processes such as waves, currents,drying events, etc.

    Beds or strata

    Cross-bedding Graded beds

    Ripple marks

    -Current ripple marks (asymmetrical ripples)Oscillation or wave ripple marks(symmetrical ripples)

    Mud cracks

    Sedimentary Structures

    Structures formed during deposition

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    1-4, after deposition 5,6

    1 2 3

    4 5 6

    Ripple marks

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    Ripple marks

    Graded bedding, Jurassic of New

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    Jersey

    Graded bedding

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    Graded bedding

    kasar

    halus

    kasar

    halus

    mudcracks bagaimana terjadi?

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    mudcracks bagaimana terjadi?

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    rounding

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    rounding

    sorting

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    sorting

    High energy enviroment Low energy enviroment

    varves

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    varves

    Cross stratification (berlaku semasa

    t i i i l t)

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    transgression-regression air laut)

    Important note

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    Important note

    Descriptive properties => interpretiveproperties

    Geology => engineering

    Objective: to aid planning, design,

    construction, mitigation, conservation,

    preservation

    Sedimentary Environments

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    Sedimentary environments are places where

    sediments accumulate and sedimentary rocksform. They can be grouped into:

    Terrestrial environments (non-marine)

    Rivers (fluvial environment)/sungai)

    Alluvial fans (kipas lanar)

    Lakes (lacustrine environment)/tasik

    - Swamps/paya

    - Deserts (aeolian environment)

    - Glacial environments

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    Transitional environments (at the

    transition between the marine and non-marine environments)

    Beach and barrier islands

    Delta Lagoons

    Estuaries

    M i i t

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    Marine environments

    Continental shelf Continental slope and rise (deep sea fans)

    Abyssal plain

    Reefs (karang)

    Alluvial fan

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    Alluvial fan

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    Enviroment of sedimentary rx

    SEDIMENTARY ENVIROMENTS

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    AGENTS &

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    AGENTS &

    ENERGYSOURCES

    ALLUVIAL

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    ALLUVIAL

    WIND ACTION (Eolian)

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    WIND ACTION (Eolian)

    Continental enviroment: fluvial

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    Continental enviroment: fluvial

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    layering

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    beach

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    Marine environment

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    Depositional environments

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    Model for landform development

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    Fossils

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    Fossils are the remains or traces of

    prehistoric life.

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    Facies - the characteristics of a unit ofsediments, which can be used to interpret

    the depositional environment.

    Batuan mendak

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    Batuan hos kepada petroleum dan gas asli

    Mendapan mineral spt Cu, Pb, Zn, Tungsten

    dll

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    a bit about Si

    14Si

    www.webelements.com

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    28.0855(3)The essentials

    Name: silicon

    Symbol: Si Atomic number: 14

    Atomic weight: 28.0855 (3) r

    CAS Registry ID: 7440-21-3

    Group number: 14

    Group name: (none) Period number: 3

    Block: p-block

    Description

    Here is a briefdescription of silicon.

    Standard state: solid at 298 K Colour: dark grey with a bluish tinge

    Classification: Semi-metallic

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    Important facts

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    Hydrolysis and condensation of substitutedchlorosilanes can be used to produce a verygreat number of polymeric products, orsilicones. These range from liquids to hard,

    glasslike solids with many useful properties. Elemental silicon transmits more than 95%

    of all wavelengths of infrared and and hasbeen used in lasers to produce coherent

    light at 456 nm.

    Isolation

    Here is a brief summary of the isolation of silicon.

    There is normally no need to make silicon in the

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    There is normally no need to make silicon in thelaboratory as it is readily available commercially. Silicon

    is readily available through the treatment of silica, SiO2,with pure graphite (as coke) in an electric furnace.

    SiO2 + 2C Si + 2CO

    Under these conditions, silicon carbide, SiC, can form.However, provided the amount of SiO2 is kept high,

    silicon carbide may be eliminated. 2SiC + SiO2 3Si + 2CO

    Very pure silicon can be made by the reaction of SiCl4with hydrogen, followed by zone refining of the resultantsilicon.

    SiCl4 + 2H2 Si + 4HCl

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    Fakta penting mengenai Malaysia

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    Most cities and large towns in the

    Peninsula are located on a thin

    surface alluvium over limestoneand granite.

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    Malaysia is generally formed by highland,floodplain, and coastal zones (Figure 1.2 ).

    In the Peninsula, the Banjaran Titiwangsa

    from north to south divides the West Coastand East Coast states, while in Sarawak the

    Banjaran Kapuas Hula and Banjaran Iran

    border Indonesia. All of these ranges aregoverned by virgin forest

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    Malaysia is warm and humid throughout theyear, as characterised by the equatorial

    climate, and has an average annual rainfall

    of more than 2500 mm with spatial variationshown in Figure 1 . 3 .

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    In the Peninsula wettest area is Taiping in Perakwhilst the driest is Kuala Pilah in Negeri Sembilan

    (Figure 1 . 5 ).

    Average daily temperatures range from a

    minimum of 25o C to a maximum of 33o C.

    Relative humidity is high, sometimes exceeding

    80%. Daytime cloudy hours are also high while

    haze lately is a frequent occurrence that willcontribute to acid rains.

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    Next lecture

    on metamorphic rocks