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UNIVERSITI TEKNIKAL MALAYSIA MELAKA Study of the Epoxy Resin Bonding Process of Aluminum Alloy : Chemical Pickling Process (Sulphuric Acid) This report submitted in accordance with requirement of the Universiti Teknikal Malaysia Melaka (UTeM) for the Bachelor Degree of Manufacturing Engineering in (Manufacturing Process) with Honours. by MOHAMMAD ASA’ARI B. RAHMAT Faculty of Manufacturing Engineering April 2009

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Page 1: UNIVERSITI TEKNIKAL MALAYSIA MELAKA - eprints.utem.edu.myeprints.utem.edu.my/6361/1/Study_Of_The_Epoxy_Resin_Bonding_Process_Of...disertasi bagi pengajian secara kerja kursus dan penyelidikan,

UNIVERSITI TEKNIKAL MALAYSIA MELAKA

Study of the Epoxy Resin Bonding Process of Aluminum Alloy :

Chemical Pickling Process (Sulphuric Acid)

This report submitted in accordance with requirement of the Universiti Teknikal

Malaysia Melaka (UTeM) for the Bachelor Degree of Manufacturing Engineering in

(Manufacturing Process) with Honours.

by

MOHAMMAD ASA’ARI B. RAHMAT

Faculty of Manufacturing Engineering

April 2009

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UTeM Library (Pind.1/2007)

UNIVERSITI TEKNIKAL MALAYSIA MELAKA

BORANG PENGESAHAN STATUS TESIS*

JUDUL: STUDY OF THE EPOXY RESIN BONDING PROCESS OF ALUMINIUM ALLOY :

CHEMICAL PICKLING PROCESS (SULPHURIC ACID)

SESI PENGAJIAN: 2/2008-2009

Saya MOHAMMAD ASA’ARI BIN RAHMAT

mengaku membenarkan tesis (PSM/Sarjana/Doktor Falsafah) ini disimpan di Perpustakaan Universiti Teknikal Malaysia Melaka (UTeM) dengan syarat-syarat kegunaan seperti berikut:

1. Tesis adalah hak milik Universiti Teknikal Malaysia Melaka dan penulis. 2. Perpustakaan Universiti Teknikal Malaysia Melaka dibenarkan membuat salinan

untuk tujuan pengajian sahaja dengan izin penulis. 3. Perpustakaan dibenarkan membuat salinan tesis ini sebagai bahan pertukaran

antara institusi pengajian tinggi.

4. **Sila tandakan (√)

SULIT

TERHAD

√ TIDAK TERHAD

(Mengandungi maklumat yang berdarjah keselamatan atau kepentingan Malaysia yang termaktub di dalam

AKTA RAHSIA RASMI 1972)

(Mengandungi maklumat TERHAD yang telah ditentukan

oleh organisasi/badan di mana penyelidikan dijalankan)

(TANDATANGAN PENULIS)

Alamat Tetap: NO 12, JALAN GELAM 11, TAMAN RINTING, 81750, MASAI, JOHOR DARUL TAKZIM

Tarikh: _______________________

Disahkan oleh:

(TANDATANGAN PENYELIA)

Cop Rasmi:

Tarikh: _______________________

* Tesis dimaksudkan sebagai tesis bagi Ijazah Doktor Falsafah dan Sarjana secara penyelidikan, atau disertasi bagi pengajian secara kerja kursus dan penyelidikan, atau Laporan Projek Sarjana Muda (PSM). ** Jika tesis ini SULIT atau TERHAD, sila lampirkan surat daripada pihak berkuasa/organisasi berkenaan dengan menyatakan sekali sebab dan tempoh tesis ini perlu dikelaskan sebagai SULIT atau TERHAD.

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FAKULTI KEJURUTERAAN PEMBUATAN

Rujukan Kami (Our Ref) : 15 Oktober 2012 Rujukan Tuan (Your Ref):

Pustakawan Perpustakaaan Universiti Teknikal Malaysia Melaka UTeM, No 1, Jalan TU 43, Taman Tasik Utama, Hang Tuah Jaya, Ayer Keroh, 75450, Melaka Saudara, PENGKELASAN TESIS SEBAGAI SULIT/TERHAD - TESIS SARJANA MUDA KEJURUTERAAN PEMBUATAN (PROSES PEMBUATAN): MOHAMMAD ASA’ARI BIN RAHMAT TAJUK: STUDY OF THE EPOXY RESIN BONDING PROCESS OF ALUMINIUM ALLOY : CHEMICAL PICKLING PROCESS (SULPHURIC ACID) Sukacita dimaklumkan bahawa tesis yang tersebut di atas bertajuk “ STUDY OF THE EPOXY RESIN BONDING PROCESS OF ALUMINIUM ALLOY : CHEMICAL PICKLING PROCESS (SULPHURIC ACID)” mohon dikelaskan sebagai terhad untuk tempoh lima (5) tahun dari tarikh surat ini memandangkan ia mempunyai nilai dan potensi untuk dikomersialkan di masa hadapan. Sekian dimaklumkan. Terima kasih. “BERKHIDMAT UNTUK NEGARA KERANA ALLAH” Yang benar, WAN HASRULNIZZAM WAN MAHMOOD Pensyarah, Fakulti Kejuruteraan Pembuatan (Penyelia Bersama) 06-2332122

s.k. - Penyelia Utama: MOHD FAIRUZ BIN DIMIN

UNIVERSITI TEKNIKAL MALAYSIA MELAKA

Karung Berkunci 1200, Ayer Keroh, 75450 Melaka

Tel : 06-233 2421, Faks : 06 233 2414 Email : [email protected]

00826
Cross-Out
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APPROVAL

This report is submitted to the Faculty of Manufacturing Engineering of UTeM as a

partial fulfillment of the requirements for the degree of Bachelor of Manufacturing

Engineering (Manufacturing Process). The members of the supervisory committee are as

follow:

(Signature of Supervisor)

--------------------------------------

(Official Stamp & Date)

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DECLARATION

I hereby, declared this report entitled “Study of the Epoxy Resin Bonding Process of

Aluminum Alloy : Chemical Pickling Process (Sulphuric Acid)” is the results of my own

research except as citied in references.

Signature : ………………………………………....

Author’s Name : MOHAMMAD ASA’ARI B RAHMAT

Date : 13 JUNE 2009

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ABSTRACT

Metal bonding is a process adhesive or epoxy resin that used to bond thin material lap

joints. This process as an alternative method to change others joint method such as spot

welding and riveting. Hence, the purpose of this report is to study of the epoxy resin

bonding process of aluminum alloy through several process. Before the process is

operated, the surface of aluminum alloy will be rough and be pre-treated using sulphuric

acid. Then the test sample will be tested using Universal Testing Machine for tensile

strength test. The project will analyze difference concentration and immersion time of

pickling chemical and from the result we can determine the best Al-Al bonding

technique. Type of material that we use in this study is Aluminum Alloy 2014/2024 T3,

epoxy resin and sulphuric acid. Machine that involve in this study Universal Testing

Machine model Shimadzu, AG-100kNI in Material Lab Faculty of Manufacturing

Engineering UTeM and SEM microscope. The purpose of this study also to find the best

aluminum-aluminum joint method. Other joint method that we can compare is riveting

and spot welding.

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ABSTRAK

‘Metal Bonding’ adalah satu bahan pelekat atau bahan epoksi yang digunakan untuk

melekatkan bahan yang nipis untuk cantuman bertindih. Proses ini sebagai satu kaedah

alternatif untuk menukar lain-lain kaedah pengikat seperti kimpalan bintik dan ‘rivet’.

Oleh itu, tujuan laporan ini adalah untuk mengkaji pelekatan aluminium aloi

menggunakan bahan epoksi melalui beberapa proses sampingan. Sebelum proses

dikendalikan, permukaan aluminum aloi akan dikasarkan sebelum ditindakbalaskan

menggunakan asid sulfurik. Kemudian sampel ujian akan di uji menggunakan ‘Universal

Testing Machine’ untuk ujian ketegangan. Projek ini juga akan menganalisis tahap asid

dan masa rendaman aluminium aloi ke dalam asid sulfurik dan daripada hasil itu kami

dapat menentukan teknik pelekat terbaik untuk aluminium aloi- aluminium aloi. Jenis

bahan yang kami gunakan dalam kajian ini adalah Aluminum Alloy 2014/2024 T3,

bahan epoksi dan asid sulfurik. Mesin yang terlibat dalam projek ini adalah ‘Universal

Testing Machine model Shimadzu AG-100kNI yang terdapat dalam Makmal

Kejuruteraan Bahan Fakulti Kejuruteraan Pembuatan UTeM dan mikroskop SEM.

Tujuan kajian ini juga untuk mencari kaedah terbaik pelekatan antara aluminum

aluminum. Kaedah pelekatan lain yang kami boleh bandingkan adalah rivet dan

kimpalan bintik.

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DEDICATION

This thesis gratefully dedicated to my beloved mother, father, brother, sister and my

friend. Thank you for your continuous support.

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ACKNOWLEDGEMENT

First of all, thanks to Allah S.W.T for his blessing and guidance in

accomplishing this research.

Sincerely, I would like to express my highest appreciation to my supportive

academic supervisor, Mr Mohd Fairuz B Dimin for his supervision and support in

completing this thesis. His knowledge and experience is really assisting me to accomplish

this research successfully.

I also like to acknowledge to laboratory technicians, who has been so warmth and

kind to provide sincere assistance and good cooperation during the training period. Their co-

operation is much appreciated.

Last but not least, I would like to convey my appreciation to all the staff of Faculty

of Manufacturing Engineering UTeM, my friend and colleagues for their support and their

help in the project. Thank you.

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TABLE OF CONTENTS

Abstract…………………………………………………………………………………...i

Abstrak……………………………………………………………………………….…..ii

Dedication……………………………………………………………………...………..iii

Acknowledgement……………………………………………………………………….iv

Table of Content……………………………………………………………………….....v

List of Figure……………………………………………...………………………….…..v

List of Table…………………………………………………………………..….……...vi

1.0 CHAPTER 1

INTRODUCTION...………………………………………………………………… …1

1.1 Background of the research .......................................................................................... 1

1.2 Problem statement ........................................................................................................ 1

1.3 Objective ...................................................................................................................... 2

1.4 Scope of Project ........................................................................................................... 2

1.5 Aluminium Alloy ......................................................................................................... 2

1.6 Epoxy resin .................................................................................................................. 3

1.7 Chemical Pickling ........................................................................................................ 4

1.8 Sulphuric Acid ............................................................................................................. 5

1.9 Universal Testing Machine (UTM) .............................................................................. 5

2.0 CHAPTER 2

LITERATURE REVIEW ................................................................................................ 6

2.1 Adhesive Bonding ....................................................................................................... 6

2.1.1 Introduction .......................................................................................................... 6

2.1.2 The advantages of the process.............................................................................. 7

2.1.3 The limitation of the process ................................................................................ 7

2.1.4 Basic Loading condition for adhesive bonded joints ........................................... 8

2.2 Material used ............................................................................................................. 10

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2.2.1 Aluminium Alloy ................................................................................................. 10

2.2.2 Epoxy resin .......................................................................................................... 12

2.2.3 Surface preparation .............................................................................................. 13

2.2.3.1 Preparation of metal surface........................................................................ 13

2.3 Chemical Pickling ...................................................................................................... 14

2.3.1 Sulphuric Acid .................................................................................................... 14

2.4 Universal Testing Machine (UTM) ............................................................................ 15

2.4.1 Specification of UTM in UTeM Material Lab ................................................... 15

2.4.2 Tensile Strength Test..................................................................................... 16

2.4.2.1 Specification of UTM in UTeM Material Lab…………………17

2.5 Laser Cutting Machine……………………………………………………………...17

3.0 CHAPTER 3

METHODOLOGY……………………………………...……………………………..19

3.1 Introduction…………………………………………………………………………19

3.2 Flow chart of project………………………………………………………………..20

3.3 Preparation of experiment…………………………..……………………………...21

3.3.1 Aluminium Alloy……………………………………………………………….21

3.4 Clean the surface using ultrasonic bath…………………………………………….22

3.5 Chemical Pickling…………………………………………………………………..23

3.6 Bonding Process using epoxy resin…………………………………………………25

3.7 Curing in room temperature………………………………………………………...26

3.8 Tensile Test using UTM…………………………………………………………….26

3.9 Gantt Chart Of The Study…………………………………………………………...27

4.0 CHAPTER 4

RESULT AND DISCUSSION………………………………………………………...29

4.1 Different concentration level……………………………………………………29

4.1.1 Ultimate Strength Graph………………………………………………...32

4.2 Different immersion time……………………………………………………….34

4.2.1 Ultimate Strength Graph………………………………………………...38

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4.1 Bonding without chemical pickling process……………………………………39

5.0 CHAPTER 5

CONCLUSION AND SUGGESTION………………………….…………………….40

5.1 Conclusion………………………………………………………………………40

5.2 Suggestion………………………………………………………………………41

REFERENCES………………………………………………………………………...42

APPENDIX A……………………………………………………………….………….44

APPENDIX B…………………………………………………………………………..45

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LIST OF FIGURES

2.1: Five basic loading conditions for adhesive bonded joints: 9

2.2 Bonded joint configurations 9

2.3 Content of epoxy resin 12

2.4 Universal Testing Machine in UTeM 15

2.5 Stress vs. Strain Curve for Ductile Material 16

2.6 Laser Beam Machine 18

3.1: The flow chart of the project methodology 20

3.2: Design of specimen 21

3.3: Cut in the middle of specimen 22

3.4 Ultrasonic Bath S30H 22

3.5 Pickling Process 24

3.6 Bonding area 25

3.7 Bonding Process 25

3.8 Temperature and Relative Humidity 25

3.9 Tensile Strength Test 26

4.1 Result for beaker 1 (concentration level) 30

4.2 Result for beaker 2 (concentration level) 30

4.3 Result for beaker 3 (concentration level) 31

4.4 Result for beaker 4 (concentration level) 31

4.5 Result for beaker 5 (concentration level) 32

4.6 Graph of Breaking Point for Different Concentration 33

Level Experiment

4.7 The surface of adhesive after tensile strength test 34

4.8 Result for beaker 1 (immersion time) 35

4.9 Result for beaker 2 (immersion time) 36

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4.10 Result for beaker 3 (immersion time) 36

4.11 Result for beaker 4 (immersion time) 37

4.12 Result for beaker 5 (immersion time) 37

4.13 Graph of Breaking Point for Different immersion 38

time Experiment

4.14 Graft of Breaking Point for specimen without chemical 39

pickling process

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LIST OF TABLES

2.1 Chemistry data of aluminium alloy 11

3.1 Concentration Level 23

3.2 Immersion Period 24

3.1: Gantt chart of the study for Projek Sarjana Muda 1 (PSM 1) 27

3.2: Gantt chart of the study for Projek Sarjana Muda 1 (PSM 2) 28

4.1 Concentration Level 29

4.2 Breaking Point result 32

4.3 Immersion Time 35

4.4 Breaking Point 38

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LIST OF ABBREAVIATION, SYMBOLS, SPECIALIZED

NOMENCLATURE

A - Area

Al - Aluminium

ANSI - American National Standards Institutes

ASTM - American Standard for Testing and Materials

CO2 - Carbon Dioxide

DIN - Deutsches Intitut für Normung ( German Institues for

Standardization)

F - Force

g - Gram

H2SO4 - Sulphuric Acid

ISO - International Standard Organization

M - Mass

Nd : YAG - Neodymium : yttrium-aluminium-garnet

Nd - Glass, ruby

RH - Relative Humidity

UTM - Universal Testing Machine

Vs - Versus

% - Percentage

ºC - Degrees Celsius

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CHAPTER 1

INTRODUCTION

1.1 Background of the research

Metal bonding is a process in which structural adhesives are primarily used to

bond thin material lap joints, replacing rivets or spot welds that are commonly used in

these applications. Metal bonding adhesives also eliminate gaps, bulges, and protruding

fasteners on aircraft exterior surfaces, thereby reducing drag forces on the aircraft. As an

aircraft design consideration, metal bonding via adhesives is an important factor in

facilitating sonic dampening and extending the fatigue life of aircraft components.

Adhesive bonding has gained increased acceptance in manufacturing ever since

its use on a large scale: the assembly of load-bearing component in aircraft during World

War II (1939-1945). Adhesive are available in various forms: liquid, paste, solution,

emulsion, powder, tape, and film. When applied, adhesives typically are about 0.1 mm

thick.

1.2 Problem Statement

Aluminum Alloy 2018 sheet metal are pre-treated using the chemical pickling

process before being bonded using epoxy resin. The test sample are then tested for tensile

strength using the Universal Testing Machine (UTM). The project will analyze different

concentration level and immersion period of pickling chemical.

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1.3 Objective

1. To analyze different concentration level and immersion period of pickling chemical

between aluminum alloy and H2SO4 before the aluminum will be bonded using

epoxy resin.

2. To determine the best concentration level and immersion time of H2SO4.

3. Analyzing the UTM test data.

1.4 Scope of Study

The scope of this project is to analyze different concentration level and immersion

period of pickling chemical between aluminum alloy and H2SO4 before the aluminum

will be bonded using epoxy resin. The aluminum alloy grade that will be use in this

experiment is Aluminium Alloy sheet 2018 with thickness 0.8mm. After the bonding

process, the sample will analyze using Universal Testing Machine (UTM) model

Shimadzu, AG-100kNI to make the tensile strength test. The concentration level of

H2SO4 that used is 5%, 10%, 15%, 20%, and 25% with 5 minutes immersion time. For

different immersion time, the period that used is 1 minutes, 2 minutes, 3 minutes, 4

minutes and 5 minutes. Then the result or data can define the best concentration level and

immersion time period of pickling chemical. The result also will compare to the test

sample without pickling process. It is important to show that there are some changes to

the strength of aluminium alloy 2018 before and after pickling process

1.5 Aluminum Alloy

Aluminum alloys are alloys of aluminum, often with copper, zinc, manganese,

silicon, or magnesium. They are much lighter and more corrosion resistant than plain

carbon steel, but not quite as corrosion resistant as pure aluminum. Bare aluminum alloy

surfaces will keep their apparent shine in a dry environment due to the formation of a

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clear, protective oxide layer. Galvanic corrosion can be rapid when aluminum alloy is

placed in electrical contact with stainless steel, or other metals with a more negative

corrosion potential than the aluminum alloy, in a wet environment. Aluminum alloy and

stainless steel parts should only be used together in water-containing systems or outdoor

installations if provision is made for either electrical or electrolytic isolation between the

two metals.

Aluminum alloys with a wide range of properties are used in engineering

structures. Alloy systems are classified by a number system (ANSI) or by names

indicating their main alloying constituents (DIN and ISO). Selecting the right alloy for a

given application entails considerations of strength, ductility, formability, weld ability

and corrosion resistance to name a few. Aluminum is used extensively in modern aircraft

due to its high strength to weight ratio.

In this experiment, type of aluminum alloy use is 2018. The International Alloy

Designation System is the most widely accepted naming scheme for wrought alloys. Each

alloy is given a four-digit number, where the first digit indicates the major alloying

elements.

1.6 Epoxy Resin

In chemistry, epoxy or polyepoxide is a thermosetting epoxide polymer that cures

(polymerizes and crosslinks) when mixed with a catalyzing agent or "hardener". Most

common epoxy resins are produced from a reaction between epichlorohydrin and

bisphenol-A. Epoxy adhesives are a major part of the class of adhesives called

"structural adhesives" or "engineering adhesives" (which also includes polyurethane,

acrylic, cyanoacrylate, and other chemicals). These high-performance adhesives are used

in the construction of aircraft, automobiles, bicycles, boats, golf clubs, skis, snow boards,

and other applications where high strength bonds are required. Epoxy adhesives can be

developed to suit almost any application. They are exceptional adhesives for wood,

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metal, glass, stone, and some plastics. They can be made flexible or rigid, transparent or

opaque/colored, fast setting or extremely slow setting. Epoxy adhesives are almost

unmatched in heat and chemical resistance among common adhesives.

1.7 Chemical Pickling

Chemical pickling in bonding is the process to pre-treat the surface of material.

Pickling is a method of surface cleaning and preparation that is achieved through

immersion of metals in dilute acids. Pickling is used in metal working industries to

remove scales, tarnish, or oxides. Pickling can be accomplished with a variety of different

acids. Acids used for pickling include sulfuric, hydrochloric, nitric, phosphoric and

various other mixtures of these.

Pickling is usually carried out by immersing metals into large baths of acid

solution but pickling can also involve spraying or flowing the solution over the specimen.

The overall goal of pickling is to remove scale from the base metal without loss from

dissolving the metal itself. This is usually accomplished through the use of inhibitors in

the pickling solution. If the scale could somehow be removed from the surface uniformly

acid attack of the base metal wouldn't be a problem as the sample could be removed from

the solution as soon as the scale was removed. Since scale is removed faster from some

areas an uninhibited acid solution would begin dissolving base metal in those areas

before all of the scale is removed.

The pickling process breaks down in the following way. First the metal must be

cleaned and prepared for the pickling process. This step includes removing any material

from the metal that would prevent contact of the pickling acid with the surface. Generally

this involves removing any oils on the surface. This is accomplished by either solvent or

alkali cleaning. In this experiment, the ultrasonic bath is use. The next step is the actual

pickling process. After pickling the metal is treated in preparation for coating. After

pickling the metal is run through a cold clean water rinse to remove the film of pickling

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acids and salts that cling to the surface. These actually cause corrosion even under

coatings if they are not removed. The film can be difficult to remove if it dries so rinsing

must occur immediately. After the cold water rinse the metal undergoes a final hot rinse

in boiling weak alkaline solution. This creates an alkaline surface that does not rust

rapidly. Prior to painting the surface pH must be adjusted to ensure proper adhesion of

the coating to the surface. This is achieved by a phosphoric or chromic acid solution.

1.8 Sulphuric Acid

Sulphuric acid is a strong mineral acid with the molecular formula H2SO4. It is

soluble in water at all concentrations. It was once known as oil of vitriol, coined by the

8th-century alchemist Jabir ibn Hayyan after his discovery of the chemical. The H2SO4

that used is bought from the hardware shop.

1.9 Universal Testing Machine (UTM)

A Universal Testing Machine otherwise known as a materials testing machine/

test frame is used to test the tensile and compressive properties of materials. Such

machines generally have two columns but single column types are also available. Load

cells and extensometers measure the key parameters of force and deformation as the

sample is tested. These machines are widely used and would be found in any materials

testing laboratory.

A typical testing system is comprised of a materials testing machine/test frame, control

and analysis software, and critically, the test fixtures, accessories, parts and devices used

to hold and support the test specimen.

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CHAPTER 2

LITERATURE REVIEW

2.1 Adhesive Bonding

2.1.1 Introduction

Higgins, A. (2000) said that adhesive bonding has been used in the manufacture

of primary aircraft fuselage and wing structures for over 50 years. As such, it is a direct

competitor process to riveted structures but not as dominant. Metal bonding is a process

in which structural adhesives are primarily used to bond thin material lap joints, replacing

rivets or spot welds that are commonly used in these applications. Metal bonding

adhesives also eliminate gaps, bulges, and protruding fasteners on aircraft exterior

surfaces, thereby reducing drag forces on the aircraft. As an aircraft design consideration,

metal bonding via adhesives is an important factor in facilitating sonic dampening and

extending the fatigue life of aircraft components.

David, E. and Lazar, A. (2003) states that the bonding process is when adhesive

was applied onto the bonding surface. The remaining layer of adhesive was as thin as

possible, about 0.05–0.08 mm. As is the case with chemical reactions, rapidity of

hardening depends on the ambient temperature or the temperature of the work piece.

Wheeler, M.J. (1987) classify the benefits of adhesive bonding have been

demonstrated by a number of car manufacturers in concept cars and low volume niche

products, e.g. Jaguar's XJ220, Ford's AIV , Rover's ECV3, the Lotus Elise, and to a

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limited extent in Honda's NSX. Not least of these benefits is that adhesive bonding does

not distort the components being joined as arc-welding has been shown to do.

2.1.2 The advantages of the process are:

1. Barnes, T.A. and Pashby, I.R. (1998) said adhesive bonding offers improved joint

stiffness compared to mechanical fasteners or spot-welds because it produces a

continuous bond rather than a localized point contact. This results in a more

uniform stress distribution over a larger area.

2. A well designed joint will absorb energy well, and tend to have good noise and

vibration damping properties.

3. The smooth joint produced reduces stress concentrations at the joint edges thereby

providing good fatigue resistance

4. Adhesive bonds are inherently high strength in shear.

5. Adhesive bonds are inherently high strength in shear ;

6. Adhesive bonding has tended to be regarded as a comparatively low cost process in

terms of equipment.

7. Kalpakjian, S. (1992) classify that the adhesive is essentially dual purpose in this

type of application as well as providing mechanical strength, the adhesive seals the

joint against moisture and debris ingress

8. Kalpakjian, S. (1992) classify that it is possible to join dissimilar and otherwise

incompatible materials. Dissimilar metals can be joined in this way, since the

adhesive layer prevents intimate contact which could otherwise lead to galvanic

corrosion

2.1.3 The limitation of the process are:

1. Barnes, T.A. and Pashby, I.R (1998) said current high performance adhesives are

epoxy or solvent based systems, giving rise to considerable environmental

concerns. The health and safety hazards involved in the use of these substances

implies significant costs in providing adequate fume extraction, protective clothing

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and adequate provision for fire protection storage. Given current environmental

concerns, there is also the possibility that these substances may eventually be

banned from use by future legislation. Alternative adhesives such as Corobond

eliminate such issues but exhibit inferior mechanical properties, particularly with

regard to impact strength.

2. Structural adhesives require heat curing. The utilization of the body-in-white (BIW)

paint bake cycle has been cited as a possible economic solution, obviating the need

for an additional processing stage. It is however, important to note that an intent to

replace pressed metal body panels with polymeric panels, paint-coated as an

integral part of the injection molding process would however invalidate this

particular solution.

3. There are also foreseeable difficulties with extensive utilization of adhesive joints in

volume production. Adhesives have a limited shelf-life and provision must be made

for this by materials control. Despite increasingly sophisticated systems designed to

counter problems such as increasing viscosity over time, the adhesive dispensers are

still likely to require regular cleaning and therefore planned routine maintenance to

prevent problems.

4. Adhesive joints are inherently weak in peel and vehicle design would need to take

account of this, particularly with regard to crashworthiness.

2.1.4 Basic Loading condition for adhesive bonded joints

Adderley, C.S (1988) states that in practice, a bonded structure often has to

sustain a combination of tensile, compressive, shear, cleavage and peel stresses.

Therefore in order to minimize the peel stresses experienced by a joint, thereby

substantially increasing its robustness, engineers generally use some form of lap shear

joint.