hot-dip galvanizing

22
Ptg. de la Masìa, 13 bxos LD6 08349 Cabrera de Mar – Barcelona (España) Tel: +34 93 754 17 47– Fax: +34 93 754 16 52 [email protected] SOCOVRAI ®

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Presentation of the hot-dip galvanising process and of the different parameters that are important when choosing one product over another. There are two suggestions for different types of treatment lines: a fully acid line with enhanced protection for rough environments needing passivation and another line with alkaline degreasing for extremely greasy parts.

TRANSCRIPT

Ptg. de la Masìa, 13 bxos LD608349 Cabrera de Mar – Barcelona (España) Tel: +34 93 754 17 47– Fax: +34 93 754 16 [email protected]

SOCOVRAI®

Protect steel & iron againstcorrosion

• A Zn layer is chemically attached to the steel surface.

• Zn corrodes slower than iron and, thus, protects

Hot-dip galvanizing

• Zn corrodes slower than iron and, thus, protects iron from corroding.

• Very strong protection against corrosion.

• Different metals (Ni, Cr…) are attached to the base metal surface.

• Used for high-gloss applications.

Electroplating

HDG is used in heavy-dutyindustries

Building & Construction

Street Furniture & Road Safety

Wire frameWire frame

Utilities & Piping

Agricultural-used steel

Transportation & Automotive

Fasteners

• Acid (cold, pre-etching)• Alkaly (warmed, needs

rinsing off)Degreasing

• Mechanic• Water-based dilution: acid or alkalyEtching

Rinsing

Rinsing

Hot-dip galvanising stages

• ZnCl2 and NH4Cl double and triple salts

• ZnCl2Flux

• Protection against corrosionGalvanising

• Protection against white corrosionPassivation

Rinsing

Drying

Our productsproducts

DEGREASING

GALVANISINGPASSIVATION

ETCHING

FLUX

ANGEM proposes the full range of products

PS series

Additives

Passivants

IC series

Additives

Additives

Salts

SOCOVRAI®PSAG

SOCOVRAI®PSJ

AcidSOCOVRAI®PSB

SOCOVRAI®PSMM

Alkaly

Degreasers

PSJ

SOCOVRAI®PS9M

PSMM

SOCOVRAI®PS198S

SOCOVRAI®PS3xE (electrolithic)

How to choose a degreaser

Dirt type

Shape and quanity of

partsAlloy type

Degreaser

Processcost

Form of application

Advantages of acid degreaser

Acie Alkaly

SOCOVRAI®IC111

SOCOVRAI®IC115

Corrosioninhibitor

SOCOVRAI®AF132

SOCOVRAI®AH131N

Additives

Etching

IC115

SOCOVRAI®IC33

SOCOVRAI®IC120

AH131N

Reduce Fe concentration

A corrosion inhibitor improvesetching

Avoid over-etching

• Higher temperature• Higher HCl

concentration

Difficult to control the acid attack on the metal

Optimum etching requires a balance between HCl y Fe

concentration

• Higher Fe concentration

Etchingspeed

Reduce bath activity

Decapado óptimo en HCl a 20ºC

200

250

300

Co

nc.

de H

ierr

o /

(g

/L)

Exhausted bath Renovate bath

A CI enlarges the margin of etching

0

50

100

150

0 50 100 150 200 250Conc. HCl / (g/L)

Co

nc.

de H

ierr

o /

(g

/L)

Tiempos mayores Óptima Saturación

HCl attacks base metal

A corrosion inhibitor enlarges margins

No

No VOCs

Low toxicity

No

SOCOVRAI ® IC120: environmentally friendly

SOCOVRAI®IC 120

No APEs

No ADR

Environmentally-friendly

Has alcoxylated alcohol and phosphonatedderivatives

SOCOVRAI® AH131N reduces process vapor

SocovraiAH131N

Etching with HCl

AH131N

+ AH131N

ZnCl2

Salts

SOCOVRAI®AF132

Additives

Flux

Double salt

Triple salt

SOCOVRAI®ATH3

SOCOVRAI®AR32

Additives

Galvanizing

Passivation Tri

WithoutChrome(VI)

Passivation 22A

WithChrome(VI)

Passivation

Tri

ADL 3P

22A

Our suggestionssuggestions

PASSIVATION

High-protection acid line

DEGREASING

SOCOVRAI®

ETCHING FLUX

GALVANIZING

SOCOVRAI®

PSAG

80 – 130 g/l25ºCYearlycleaning

SOCOVRAI®

IC120 (0,3%) + AH131N (2 l/m3)

HCl] >100 g/L, [Fe3+]<140 g/LT: 25 ºC

Sel double + SOCOVRAI®

AF132 (5 g/l) + ATH3 (0,5%)

D: 1,2 – 1,26 g/l65 -70ºC

SOCOVRAI®

AR32

450ºC

DE-ZINC

SOCOVRAI®

IC 33

ADL 3P

50-70ºC

Line with alkaly degreaser

DEGREASING

SOCOVRAI®

ETCHING FLUX

GALVANIZING

RINSING

SOCOVRAI®

PSB

7 -20 %55 - 60ºCCleaningevery 6 moths

SOCOVRAI®

IC120 (0,3%) + AH131N (2 l/m3)

HCl] >100 g/L, [Fe3+]<140 g/LT: 25 ºC

Sel double + SOCOVRAI®

AF132 (5 g/l) + ATH3 (0,5%)

D: 1,2 – 1,26 g/l65 -70ºC

SOCOVRAI®

AR32

450ºC

DE-ZINC

SOCOVRAI®

IC 33

Technology

Technical support

Product Proximity

SpeedSpecialized in metal

ANGEM Specialities is:

Bath analysis

R+D

Agility

ISO 9001

Ley de envases –R.D.782/1998

Customized products

Competitive prices